ZIF-8浆液中试分离CO2/N2过程模拟及能耗分析

被引：0

作者：

黄子轩 ^{[1
]}

陈欢 ^{[1
]}

李海 ^{[1
,2
]}

王明龙 ^{[1
]}

陈光进 ^{[1
]}

刘蓓 ^{[1
]}

机构：

[1] 中国石油大学(北京)重质油国家重点实验室

[2] 中国科学院过程工程研究所绿色过程与工程重点实验室

来源：

化工学报 | 2022年 / 73卷 / 01期

关键词：

ZIF-8; 二氧化碳捕集; 填料塔; 过程模拟; 能耗分析;

D O I：

暂无

中图分类号：

TQ028.17 [];

学科分类号：

摘要：

ZIF-8/2-甲基咪唑-乙二醇-水浆液（ZIF-8浆液）可以高效低耗能地分离CO2。为了进一步评估ZIF-8浆液在填料塔中分离CO2的塔效率及能耗,使用Peng-Robinson（PR）状态方程,求出CO2和ZIF-8浆液的二元交互作用参数(kCO2),将二元交互作用参数和Aspen Plus软件进行关联,对CO2/N2多级吸收分离进行过程模拟。计算结果表明在中试填料塔中,ZIF-8浆液仅需要5块理论塔板即可将CO2浓度由20%（mol）降低至2%（mol）以下,填料塔的塔板效率为25%。对中试分离CO2/N2进行能耗计算,结果表明当解吸条件为解吸温度333 K,解吸压力0.8 MPa和空气吹扫流量200 L/h时,CO2捕集等效功最低可至0.474 GJ/t CO2。在同样条件下使用ZIF-8浆液和MEA(30%（mass）)水溶液进行碳捕集时,CO2捕集等效功分别为0.507 GJ/t CO2和0.957 GJ/t CO2,ZIF-8浆液的CO2捕集等效功仅为MEA水溶液的53%。

引用

页码：322 / 331

页数：10

共 32 条

[1] A continuous and high-efficiency process to separate coal bed methane with porous ZIF-8 slurry: Experimental study and mathematical modelling
Wan Chen
Xiaonan Guo
Enbao Zou
Mengling Luo
Mengzijing Chen
Mingke Yang
Hai Li
Chongzhi Jia
Chun Deng
Changyu Sun
Bei Liu
Lanying Yang
Guangjin Chen
[J]. GreenEnergy&Environment, 2020, 5 (03) : 347 - 363
[2] Solution processable metal-organic frameworks for mixed matrix membranes using porous liquids
Knebel, Alexander
Bavykina, Anastasiya
Datta, Shuvo Jit
Sundermann, Lion
Garzon-Tovar, Luis
Lebedev, Yury
Durini, Sara
Ahmad, Rafia
Kozlov, Sergey M.
Shterk, Genrikh
Karunakaran, Madhavan
Carja, Ionela Daniela
Simic, Dino
Weilert, Irina
Klueppel, Manfred
Giese, Ulrich
Cavallo, Luigi
Rueping, Magnus
Eddaoudi, Mohamed
Caro, Juergen
Gascon, Jorge
[J]. NATURE MATERIALS, 2020, 19 (12) : 1346 - +
[3] Separation of IGCC syngas by using ZIF-8/dimethylacetamide slurry with high CO 2 sorption capacity and sorption speed but low sorption heat[J] . Ming-Ke Yang,Yu Han,En-Bao Zou,Wan Chen,Xiao-Wan Peng,Bao-Can Dong,Chang-Yu Sun,Bei Liu,Guang-Jin Chen.Energy . 2020 (prep)
[4] Separation of Ethane from Natural Gas Using Porous ZIF-8/Water–Glycol Slurry[J] . Wan Chen,Enbao Zou,Julian Y. Zuo,Mengzijing Chen,Mingke Yang,Hai Li,Chongzhi Jia,Bei Liu,Changyu Sun,Chun Deng,Qinglan Ma,Lanying Yang,Guangjin Chen.Industrial ＆ Engineering Chemistry Research . 2019 (23)
[5] Enrichment of Hydrogen from a Hydrogen/Propylene Gas Mixture Using ZIF-8/Water-Glycol Slurry
Li, Hai
Gao, Xueteng
Jia, Chongzhi
Chen, Wan
Liu, Bei
Yang, Lanying
Sun, Changyu
Chen, Guangjin
[J]. ENERGIES, 2018, 11 (07):
[6] Heteroepitaxially Grown Zeolitic Imidazolate Framework Membranes with Unprecedented Propylene/Propane Separation Performances
Kwon, Hyuk Taek
Jeong, Hae-Kwon
Lee, Albert S.
An, He Seong
Lee, Jong Suk
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (38) : 12304 - 12311
[7] Adsorptive absorption: A preliminary experimental and modeling study on CO 2 solubility[J] . Zhigang Lei,Chengna Dai,Wenjing Song.Chemical Engineering Science . 2015
[8] Large-scale synthesis of ZIF-67 and highly efficient carbon capture using a ZIF-67/glycol-2-methylimidazole slurry[J] . Yong Pan,Hai Li,Xiao-Xin Zhang,Zhe Zhang,Xiong-Shi Tong,Chong-Zhi Jia,Bei Liu,Chang-Yu Sun,Lan-Ying Yang,Guang-Jin Chen.Chemical Engineering Science . 2015
[9] Porous liquids: a promising class of media for gas separation[J] . Zhang Jinshui,Chai Song-Hai,Qiao Zhen-An,Mahurin Shannon M,Chen Jihua,Fang Youxing,Wan Shun,Nelson Kimberly,Zhang Pengfei,Dai Sheng.Angewandte Chemie （International ed. in English） . 2015 (3)
[10] A hybrid absorption-adsorption method to efficiently capture carbon
Liu, Huang
Liu, Bei
Lin, Li-Chiang
Chen, Guangjin
Wu, Yuqing
Wang, Jin
Gao, Xueteng
Lv, Yining
Pan, Yong
Zhang, Xiaoxin
Zhang, Xianren
Yang, Lanying
Sun, Changyu
Smit, Berend
Wang, Wenchuan
[J]. NATURE COMMUNICATIONS, 2014, 5

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