Highly efficient regioselective ring openings of N-tosylaziridines to haloamines using ferric(Ⅲ) halides

被引：1

作者：

Xing Li ^{[1
]}

Zhi-Qin Sun ^{[1
]}

Hong-Hong Chang ^{[1
]}

Wen-Long Wei ^{[1
]}

机构：

[1] Department of Chemistry and Chemical Engineering, Taiyuan University of Technology

来源：

Chinese Chemical Letters | 2014年 / 25卷 / 08期

关键词：

Ring-opening N-Tosylaziridine Haloamine Ferric(III) halide Regioselectivity;

D O I：

暂无

中图分类号：

O643.36 [催化剂]; TQ138.11 [];

学科分类号：

0817 ; 081705 ;

摘要：

FeX3(X = Cl, Br) were found to be very effective reagents and powerful catalysts for regioselective ring openings of a variety of N-tosylaziridines with them to afford the corresponding b-haloamines in good to excellent yields with high regioselectivity under mild conditions. At the same time, 13 new compounds were obtained firstly. Moreover, the b-bromoamine prepared could be transferred into b-nitroamine with NaNO2 in moderate yield.

引用

页码：1174 / 1178

页数：5

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