ESR Study on the Photooxidation Mechanism of Near-Infrared Absorbing Benzothiazolone Cyanine Dye

被引:0
|
作者
Jun LI
Ping CHEN
Jiang ZHAO
De Shui ZHENG(Institute of Photographic Chemistry
Masaaki Hayami(Nippon Kankah-Shikiso Kenkyusho
机构
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ESR Study on the Photooxidation Mechanism of Near-Infrared Absorbing Benzothiazolone Cyanine Dye;
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中图分类号
O644 [光化学、辐射化学、超声波作用的化学过程];
学科分类号
070304 ; 081704 ;
摘要
In this paper, the direct photooxidation mechanism of near-infrared absorbing benzothiazolone cyanine dye has been studied by VIS absorption spectroscopy and Electron Spin Resonance (ESR).The technique of spin trapping has been successfully applied to the detection of the photoinduced formation of singlet oxygen (1O2) and superoxide (O2-). It was reveled that the singlet oxygen and superoxide anion all contributed to the photofading of cyanine dye.
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页码:711 / 714
页数:4
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