Synthesis of jet fuel additive with cyclopentanone

被引：0

作者：

Hao Tang ^{[1
,2
]}

Fang Chen ^{[1
,2
]}

Guangyi Li ^{[1
]}

Xiaofeng Yang ^{[1
]}

Yancheng Hu ^{[1
]}

Aiqin Wang ^{[1
,3
]}

Yu Cong ^{[1
]}

Xiaodong Wang ^{[1
]}

Tao Zhang ^{[1
,3
]}

Ning Li ^{[1
,3
]}

机构：

[1] State Key Laboratory of Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences

[2] University of Chinese Academy of Sciences

[3] iChEM (Collaborative Innovation Center of Chemistry for Energy Materials),Dalian Institute of Chemical Physics,Chinese Academy of Sciences

来源：

Journal of Energy Chemistry | 2019年 / 02期

基金：

中国国家自然科学基金;

关键词：

Lignocellulose; Jet fuel additive; Aldol condensation; Dehydration/rearrangement; Hydrogenation;

D O I：

暂无

中图分类号：

TE624.81 [];

学科分类号：

081702 ;

摘要：

A new route was developed for the synthesis of renewable decalin with cyclopentanone which can be derived from lignocellulose.It was found that 1,2,3,4,5,6,7,8-octahydronaphthalene could be selectively produced by the hydrogenation/dehydration/rearrangement of [1,1-bi(cyclopentylidene)]-2-one(i.e.the selfaldol condensation product of cyclopentanone) over a dual-bed catalyst system.Among the investigated catalysts,the Ru/C and Amberlyst-15 resin exhibited the highest activities for the hydrogenation of [1,1-bi(cyclopentylidene)]-2-one to [1,1-bi(cyclopentan)]-2-ol and the dehydration/rearrangement of [1,1-bi(cyclopentan)]-2-ol to 1,2,3,4,5,6,7,8-octahydronaphthalene,respectively.Using Ru/C and Amberlyst-15 resin as the first bed and the second bed catalysts,1,2,3,4,5,6,7,8-octahydronaphthalene was directly produced in high carbon yield(83.7%) under mild conditions(393 K,1 MPa).After being hydrogenated,the1,2,3,4,5,6,7,8-octahydronaphthalene was converted to decalin which can be used as additive to improve the thermal stability and volumetric heat value of jet fuel.

引用

页码：23 / 30

页数：8

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