STUDIES OF MAIN CHAIN DYNAMICS OF FLUORINE-CONTAINING IONOMERS BY CARBON-13 NUCLEAR MAGNETIC RELAXATION

被引:0
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作者
杨延武
王德华
裘鉴卿
钱保功
王洪祚
机构
[1] Academia Sinica
[2] Department of Chemistry
[3] Laboratory of Magnetic Resonance and Atomic and Molecular Physics
[4] Wuhan Institute of Physics
[5] Wuhan University
基金
中国国家自然科学基金;
关键词
Spin-spin relaxation; Main chain dynamics; Ionomer; VJGM Model;
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学科分类号
摘要
The carbon-13 spin-spin relaxation times of fluorine-containing ionomers are measured and motional correlation times τ;and τ;are calculated by using VJGM model . The results show that the motions of polymer main chain in ionomers become more difficult with increasing of ionization degree and contents of functional group, and depend on the fine structures and stability of ionic microdomains.
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页码:113 / 118
页数:6
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