Synthesis, Crystal Structure and Magnetic Properties of Heptanuclear Manganese Complexes with Schiff-base Ligand

被引：0
|
作者：
杨立国 [1 ]
王鑫 [1 ]
余智超 [1 ]
张永辉 [1 ]
李书丽 [1 ]
王凯 [1 ]
牛永生 [1 ]
宋海香 [1 ]
机构：
[1] College of Chemistry and Environmental Engineering,Anyang Institute of Technology
来源：
Chinese Journal of Structural Chemistry | 2019年 / 38卷 / 12期
关键词：
manganese; schiff base; crystal structures; magnetic properties;
D O I：
10.14102/j.cnki.0254-5861.2011-2379
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
One new mixed-valence heptanuclear manganese complex, [Mn;Mn;6O;L;-（NaCH;COO）;（CH;COO）;]（1）(L = 3-ethoxy-6-((（2-hydroxyethyl）imino)methyl) phenol, was synthesized by treating the Schiff-base ligand with Mn（acac）;?4H;O and characterized by elemental analysis, IR spectra, thermogravimetric analyses and X-ray single-crystal diffraction. 1 has a similar new mixed-valence heptanuclear structure. The magnetic measurements indicate that 1 exhibits the antiferromagnetic interactions.
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收藏
页码：2135 / 2140
页数：6
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