Effect of doping Gd3+ on crystal structure and luminescent properties of Sr2SiO4:Eu2+ phosphor

被引:2
|
作者
赵聪 [1 ,2 ,3 ]
朱达川 [1 ]
高唯 [2 ]
韩涛 [3 ]
彭玲玲 [3 ]
涂铭旌 [1 ]
机构
[1] College of Materials Science and Engineering, Sichuan University
[2] Research Center for Material Interdisciplinary Science, Chongqing University of Arts and Science,Chongqing Engineering Research Center for Optoelectronic Materials and Devices
[3] Department of Chemical & Materials Engineering, The University of Auckland
基金
中国国家自然科学基金;
关键词
doping; solid-state reaction; photoluminescence; Sr2SiO4; phosphors; rare earths;
D O I
暂无
中图分类号
TN312.8 []; TQ422 [光化学物质];
学科分类号
0803 ; 0817 ;
摘要
Sr1.995–1.5xGdxSi O4:0.005Eu2+ phosphor series with x=0–0.08 mol for near-ultraviolet white light-emitting diodes(NUV w-LEDs) were synthesized via solid-state reaction method. XRD profile pattern and refinement results demonstrated that doping Gd3+ions resulted in the phase transformation(β-Sr2 Si O4→α’-Sr2 Si O4). The photoluminescence spectrum of the sample with x=0 mol displayed two emission peaks centered at 470 and 525 nm. The two-peak spectra became one-peak spectra with the Gd3+ concentration increasing. Actually, the fitting results demonstrated that the one-peak spectra were still composed of two single emission spectra. The photoluminescence intensity was improved and the CIE chromaticity coordinates were adjusted via doping Gd3+.
引用
收藏
页码:693 / 699
页数:7
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