Studies of Mixed-valence Compounds（Ⅰ）──In-Situ FTIR and UV-Visible-Near-IR Spectroelectrochemical Studies of Mixed-valence Isopolyanion Mo6O193- in Aprotic Media

被引：0

作者：

SUN Hao-ran

YANG Guo-yu

XU Jia-ning and XU Ji-qing (Department of Chemistry

机构：

来源：

Chemical Research in Chinese Universities | 1996年 / 01期

关键词：

Mixed-valence compound; Electrochemistry; In-situ spectro-electrochemistry;

D O I：

暂无

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The mixed-valence isopolyanion Mo6O193- was investigated by means of cyclic voltammographic, in-situ FTIR and UV-Visible-Near-IR spectro-electrochemicalmethods in aprotic media. The experimental results indicate that the Mo6O193-was formed whereafter Mo6O193- was reduced, (E0’ = - 0. 690 V, n = 1 ). The characteristic absorptions of Mo6O193- are 500 nm, 900 nm and 1100 nm in UV-VisibleNear-IR spectrum and 940 cm-1 in IR spectrum.

引用

页码：6 / 9

页数：4

共 25 条

[1] In-situ FTIR and UV-visible-near-IR spectroelectrochemical studies of mixed-valence isopolyanion Mo6O193- in aprotic media
Sun, HR
Yang, GY
Xu, JN
Xu, JQ
CHINESE CHEMICAL LETTERS, 1995, 6 (12) : 1059 - 1060
[2] Studies of mixed-valence compounds .1. In-situ FTIR and UV-visible-near-IR spectroelectrochemical studies of mixed-valence isopolyanion Mo6O193- in aprotic media
Sun, HR
Yang, GY
Xu, JN
Xu, JQ
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 1996, 12 (01) : 6 - 9
[3] Studies of mixed-valence compounds(I) - in-situ FTIR and UV-visible-near-IR spectroelectro-chemical studies of mixed-valence isopolyanion Mo6O193- in aprotic media
Chem Res Chin Univ, 1 (06):
[4] IN－SITU　FTIR　AND　UV－VISIBLE－NEAR－IR　SPECTROELECTROOHEMICAL　STUDIES　OF　MIXED－VALENCE　ISOPOLYANION　Mo＿6O＿（19）￣（3－）　IN　APROTIC　MEDIA
Hao Ran SUN
Gou Yu YANG
Jia Ning XU
Ji Qing XU (Department of Chemistry
Chinese Chemical Letters, 1995, (12) : 1059 - 1060
[5] Studies on mixed-valence compounds (II) - Electrochemical and in situ UV-Vis-Near-IR and FTIR spectroelectrochemical studies of mixed-valence heteropolyanion [HAs2Mo18O62](n-) in aprotic media
Zhang, SY
Sun, HR
Yang, GY
Xu, JQ
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1997, 18 (05): : 772 - 776
[6] Electrochemical and in-situ UV-visible-near-IR and FTIR spectroelectrochemical characterisation of the mixed-valence heteropolyanion PMo12O40n- (n = 4, 5, 6, 7) in aprotic media
Sun, HR
Zhang, SY
Xu, JQ
Yang, GY
Shi, TS
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 455 (1-2) : 57 - 68
[7] Electrochemical and Spectroelectrochemical studies of Mixed-Valence Heteropolyanion VMo12O40n-（n=4,5,6） in Aprotic Media
Shu Yan ZHANG
Hao Ran SUN
Ji Qing XU
Tong Shun SHl(Department of Chemistry
ChineseChemicalLetters, 1997, (10) : 909 - 912
[8] Electrochemical and spectroelectrochemical studies of mixed-valence heteropolyanion VMo12O40n-(n=4,5,6) in aprotic media
Zhang, SY
Sun, HR
Xu, JQ
Shi, TS
CHINESE CHEMICAL LETTERS, 1997, 8 (10) : 909 - 912
[9] NEAR-IR SPECTROSCOPIC STUDIES OF MIXED-VALENCE DIFERROCENE, TRIFERROCENE, AND TETRAFERROCENE DERIVATIVES
DELGADOPENA, F
TALHAM, DR
COWAN, DO
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 253 (03) : C43 - C46
[10] MOSSBAUER AND NMR-STUDIES OF MIXED-VALENCE FE2F5.7H2O AND RELATED COMPOUNDS
SAKAI, T
TOMINAGA, T
RADIOCHEMICAL AND RADIOANALYTICAL LETTERS, 1975, 22 (01): : 11 - 17

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