共 4 条
η2C70[RhCl(CO)(PPh3)2]_n配合物的合成和表征
被引:1
|作者:
杨森根
唐田
林永生
程大典
詹梦熊
郑兰荪
机构:
[1] 厦门大学化学系!厦门
来源:
基金:
高等学校博士学科点专项科研基金;
关键词:
C70[RhCl(CO)(PPh3)2]2;
C70[RhCl(CO)(PPh3)2];
合成;
表征;
D O I:
暂无
中图分类号:
O627 [元素有机化合物];
学科分类号:
摘要:
The fullerene complexes, η2-C70[RhCl(CO)(PPh3)2]_n(n=1, 2), have been prepared by the reaction of C70 with RhCl(CO)(PPh3)2 in methylbenzene at room temperature. The new complexes were characterized by UV-Vis spectra, IR, XPS and elemental analysis. The results show that the complexes of η2 form can be formed by RhCl(CO)(PPh3)2 bonding to C70 in theσ-π way. In addition, the complexes structures have been supposed.
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页码:185 / 187
页数:3
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