Novel Fréchet-type dendritic BINOL ligands and their applications in Ti(IV) complex catalyzed asymmetric addition of diethylzinc to aldehydes

被引：0
|
作者：
Liang Yin Chao Feng Wang Huan Ling Wang Rong Li Jian Tai Ma College of Chemistry and Chemical Engineering
机构：
来源：
Chinese Chemical Letters | 2007年 / 12期
关键词：
Asymmetric catalysis; BINOL; Aldehydes;
D O I：
暂无
中图分类号：
O643.32 [催化反应];
学科分类号：
081705 ;
摘要：
New Fréchet-type dendritic BINOL ligands bearing several BINOL units at the periphery have been successfully synthesized. The (dendritic BINOL) Ti(Ⅳ) complexes were proved to be efficient catalysts for the enantioselective addition of diethylzinc to aromatic aldehydes.Moreover,these ligands could be quantitatively recovered and reused at least five times without a loss of the yield and enantioselectivity.
引用
收藏
页码：1487 / 1489
页数：3
相关论文
共 50 条
  • [1] Novel Frechet-type dendritic BINOL ligands and their applications in Ti(IV) complex catalyzed asymmetric addition of diethylzinc to aldehydes
    Yin, Liang
    Wang, Chao Feng
    Wang, Huan Ling
    Li, Rong
    Ma, Jian Tai
    CHINESE CHEMICAL LETTERS, 2007, 18 (12) : 1487 - 1489
  • [2] The synthesis of dendritic BINOL ligands and their applications in the enantioselective Lewis acid catalyzed addition of diethylzinc to aldehydes
    Fan, QH
    Liu, GH
    Chen, XM
    Deng, GJ
    Chan, ASC
    TETRAHEDRON-ASYMMETRY, 2001, 12 (11) : 1559 - 1565
  • [3] The synthesis of dendritic BINOL ligands and their applications in the asymmetric addition of diethylzinc to benzaldehyde
    Yin, Liang
    Li, Rong
    Wang, Fushan
    Wang, Huanling
    Zheng, Yunfeng
    Wang, Chaofeng
    Ma, Jiantai
    TETRAHEDRON-ASYMMETRY, 2007, 18 (11) : 1383 - 1389
  • [4] Enantioselective addition of diethylzinc to aromatic aldehydes catalyzed by Ti(BINOL) complex
    Tetrahedron Asymmetry, 4 (585):
  • [5] Synthesis of new dendritic chiral BINOL ligands and their applications in enantioselective Lewis acid catalyzed addition of diethylzinc to aldehydes
    Fan, QH
    Yang, XQ
    Liu, GG
    Chen, XM
    Chan, ASC
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2003, 24 (02): : 274 - 277
  • [6] Recyclable fluorous chiral ligands and catalysts: asymmetric addition of diethylzinc to aromatic aldehydes catalyzed by fluorous BINOL-Ti complexes
    Nakamura, Y
    Takeuchi, S
    Okumura, K
    Ohgo, Y
    Curran, DP
    TETRAHEDRON, 2002, 58 (20) : 3963 - 3969
  • [7] Enantioselective Diethylzinc Addition to Aromatic Aldehydes Catalyzed by Novel Ti(IV) Complex of Three-Dentate Chiral Sulfonamide Ligands
    Dabiri, Minoo
    Salehi, Peyman
    Heydari, Seddigheh
    Kozehgary, Gholamreza
    SYNTHETIC COMMUNICATIONS, 2009, 39 (24) : 4350 - 4361
  • [8] Synthesis of modified H4-BINOL ligands and their applications in the asymmetric addition of diethylzinc to aromatic aldehydes
    Lu, Yong-Na
    Guo, Qun-Sheng
    Jiang, Fu-Yong
    Li, Jin-Shan
    TETRAHEDRON-ASYMMETRY, 2006, 17 (12) : 1842 - 1845
  • [9] The synthesis of silica-supported chiral BINOL: Application in Ti-catalyzed asymmetric addition of diethylzinc to aldehydes
    Pathak, Kavita
    Ahmad, Irshad
    Abdi, Sayed H. R.
    Kureshy, Rukhsana I.
    Khan, Noor-ul H.
    Jasra, Raksh V.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 280 (1-2) : 106 - 114
  • [10] Chiral bis(amino alcohol)oxalamides as ligands for asymmetric catalysis.: Ti(IV) catalyzed enantioselective addition of diethylzinc to aldehydes
    Blay, G
    Fernández, I
    Marco-Alelxandre, A
    Pedro, JR
    TETRAHEDRON-ASYMMETRY, 2005, 16 (06) : 1207 - 1213
12345