Hydrothermal Synthesis and Structure Characterization of Compound Zn（Hpydc）2（H2O） （pydc=pyridine-2,5-dicarboxylate）

被引：0
|
作者：
LIANG Yu-Cang HONG Mao-Chun② CAO Rong② WENG Jia-Bao (State Key Laboratory of Structural Chemistry
机构：
来源：
Chinese Journal of Structural Chemistry | 2001年 / 06期
基金：
中国国家自然科学基金;
关键词：
zinc complex; hydrothermal synthesis; crystal structure; hydrogen bond; weak interaction;
D O I：
10.14102/j.cnki.0254-5861.2001.06.006
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
The hydrothermal reaction of ZnO, H3PO4(85%), (H2NCH2CH2)2NH and H2pydc results in the formation of a discrete mononuclear zinc(II) complex Zn(Hpydc)2(H2O). It crystallizes in monoclinic space group C2/c with a = 17.9947(8), b = 7.1875(3), c = 12.5895(4) , b = 110.802(2), V = 1522.14(10) 3, Z = 4, Mr = 415.61, (C14H10N2O9Zn), Dc = 1.814g/cm3, = 16.71cm-1, F(000) = 840, R = 0.0505, wR = 0.1144. Each zinc(II) is coordinated to two nitrogen and three oxygen atoms of which two nitrogen and two oxygen atoms are from two pydc ligands, and one oxygen atom from the coordinated water molecule to form an irregular polyhedral geometry. The complex is linked further into a three-dimensional structure through the weak interactions of hydrogen bonds between the two oxygen atoms. IR spectrum of the complex is also discussed.
引用
收藏
页码：455 / 458
页数：4
相关论文
共 50 条
  • [1] Hydrothermal synthesis and structure characterization of compound Zn(Hpydc)2(H2O) (pydc=pyridine-2,5-dicarboxylate)
    Liang, YC
    Hong, MC
    Cao, R
    Weng, JB
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2001, 20 (06) : 455 - 458
  • [2] 2,2′-Azanediyldiethanaminium pyridine-2,5-dicarboxylate
    Aghabozorg, Hossein
    Saemi, Maryam
    Khazaei, Zeynab
    Amani, Vahid
    Notash, Behrouz
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O292 - U2190
  • [3] Hydrothermal synthesis, crystal structure and photoluminescent properties of a novel 3-D coordination polymer [Cd2(pydc)2(H2O)]n (pydc = pyridine-2,3-dicarboxylate)
    Han, Zheng-Bo
    Ma, Yi
    Sun, Zhen-Gang
    You, Wan-Sheng
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (08) : 844 - 847
  • [4] SYNTHESIS, CHARACTERIZATION, AND CRYSTAL STRUCTURE OF A NEW COORDINATION POLYMER, {[BA2(HPYDC)2(PYDC)(H2O)3]•H2O•(H2PYDC)}n
    Rafizadeh, Massoud
    Amani, Vahid
    Tayebee, Reza
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2008, 22 (01) : 93 - 99
  • [5] Synthesis and Structural Characterization of a Series of Novel Zn(II)-based MOFs with Pyridine-2,5-dicarboxylate Linkers
    Isaeva, Vera I.
    Belyaeva, Elena V.
    Fitch, Andrew N.
    Chernyshev, Vladimir V.
    Klyamkin, Semen N.
    Kustov, Leonid M.
    [J]. CRYSTAL GROWTH & DESIGN, 2013, 13 (12) : 5305 - 5315
  • [6] Synthesis, Structure Characterization and Photoluminescence of a Novel Complex with (6,4,4)-Network [Ce2(2,5-pydc)3(H2O)2] (2,5-pydc = Pyridine-2,5-dicarboxylic Acid)
    Qi Yan-Juan
    Bi Shu-Yun
    Yuan Xiao-Dong
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (09) : 1421 - 1425
  • [7] Synthesis,Structure Characterization and Photoluminescence of a Novel Complex with（6,4,4）-Network [Ce2（2,5-pydc）3（H2O）2]（2,5-pydc = Pyridine-2,5-dicarboxylic Acid）
    齐艳娟
    毕淑云
    苑晓冬
    [J]. Chinese Journal of Structural Chemistry, 2010, 29 (09) : 1421 - 1425
  • [8] Hydrothermal synthesis and crystal structure of [Co(2,5-pydc)(H2O)2]n • nH2O (2,5-pydc=2,5-pyridinedicarboxylate)
    Jung, Eun Ju
    Lee, U. k.
    Koo, Bon Kweon
    [J]. INORGANICA CHIMICA ACTA, 2008, 361 (9-10) : 2962 - 2966
  • [9] Preparation and structure of a two-dimensional nickel-(pyridine-2,5-dicarboxylate) coordination polymer and [Ni(pyridine-4-carboxylic acid)2(H2O)4]
    Min, D
    Yoon, SS
    Lee, CY
    Han, WS
    Lee, SW
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2001, 22 (09) : 1041 - 1044
  • [10] Hydrothermal synthesis and structural characterization of a novel three-dimensional supramolecular framework constructed by zinc salt and pyridine-2,5-dicarboxylate
    Wang, XL
    Qin, C
    Wang, EB
    Hu, CW
    Xu, L
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2004, 698 (1-3) : 75 - 80
12345