Iridium complex catalyzed hydrogen transfer reaction of unsaturated alcohols

被引：0
|
作者：
LIN Ying-Rui
MA Da-Wei
LU Xi-Yan*
机构：
来源：
Chinese Journal of Chemistry | 1988年 / 03期
关键词：
Pr; Iridium complex catalyzed hydrogen transfer reaction of unsaturated alcohols;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Hydrogen transfer reaction catalyzed by transition metal complexes has been studiedWidely. The unsaturated alcohols can be isomerized to aldehydes or ketones by intra-molecular hydrogen transfer reaction. RRC=CHCH（OH）RRRCHCHCORIn this reaction, hydrogenation of olefins and the oxidation of alcohols can be carried out sim-ultaneously under mild conditions without the addition of any other, therefore, thisreaction has useful applications in organic synthesis.
引用
收藏
页码：272 / 274
页数：3
相关论文
共 50 条
  • [1] IRIDIUM COMPLEX CATALYZED HYDROGEN TRANSFER-REACTION OF UNSATURATED SECONDARY ALCOHOLS
    LIN, YR
    MA, DW
    LU, XY
    [J]. ACTA CHIMICA SINICA, 1988, 46 (01) : 93 - 95
  • [2] BIPHASIC REDUCTION OF UNSATURATED ALDEHYDES TO UNSATURATED ALCOHOLS BY RUTHENIUM COMPLEX-CATALYZED HYDROGEN TRANSFER
    JOO, F
    BENYEI, A
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 363 (1-2) : C19 - C21
  • [3] HYDROGEN TRANSFER-REACTION OF ALLYLIC ALCOHOLS CATALYZED BY A MOLYBDENUM COMPLEX
    LIN, YGR
    LU, XY
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 251 (03) : 321 - 325
  • [4] NATURE OF THE CATALYTIC CYCLE IN IRIDIUM-COMPLEX CATALYZED HYDROGENATION OF UNSATURATED ALCOHOLS
    BROWN, JM
    DEROME, AE
    HALL, SA
    [J]. TETRAHEDRON, 1985, 41 (20) : 4647 - 4656
  • [5] IRIDIUM PENTAHYDRIDE COMPLEX CATALYZED DEHYDROGENATION OF ALCOHOLS IN THE ABSENCE OF A HYDROGEN ACCEPTOR
    LIN, YR
    MA, DW
    LU, XY
    [J]. TETRAHEDRON LETTERS, 1987, 28 (27) : 3115 - 3118
  • [6] ISOMERIZATION OF PROPARGYLIC ALCOHOLS CATALYZED BY AN IRIDIUM COMPLEX
    MA, DW
    LU, XY
    [J]. TETRAHEDRON LETTERS, 1989, 30 (16) : 2109 - 2112
  • [7] Iridium Complex-Catalyzed C2-Extension of Primary Alcohols with Ethanol via a Hydrogen Autotransfer Reaction
    Kobayashi, Masaki
    Itoh, Satoshi
    Yoshimura, Keisuke
    Tsukamoto, Yuya
    Obora, Yasushi
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2020, 85 (18): : 11952 - 11958
  • [8] SELECTIVE REDUCTION OF UNSATURATED-KETONES TO UNSATURATED ALCOHOLS CATALYZED BY AN IRIDIUM PHOSPHINE SYSTEM
    VISINTIN, M
    SPOGLIARICH, R
    KASPAR, J
    GRAZIANI, M
    [J]. JOURNAL OF MOLECULAR CATALYSIS, 1984, 24 (03): : 277 - 280
  • [9] Kinetics, mechanism, and simulation of hydrogen transfer reaction of α, β-unsaturated aldehydes to allylic alcohols
    Guo, Hui
    Li, Yuchao
    Zuo, Cuncun
    Zheng, Yanxia
    Guo, Xinpeng
    Hao, Jinguo
    Huang, Haofei
    Wang, Ming
    Ge, Tingting
    [J]. AICHE JOURNAL, 2022, 68 (07)
  • [10] Iridium-catalyzed reductive etherification of α,β-unsaturated ketones and aldehydes with alcohols
    Ouyang, Lu
    Xia, Yanping
    Miao, Rui
    Liao, Jianhua
    Luo, Renshi
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2022, 20 (13) : 2621 - 2625
12345