Synthesis and Characterization of Titania and Rare Earth Doped Titania Nanoparticles by Sol-gel Process

被引:0
|
作者
林萍
咸春颖
毛志平
郑利民
机构
[1] College of Chemistry and Chemical Engineering Donghua University
[2] College of Chemistry and Chemical Engineering Donghua University
[3] Shanghai 200051
关键词
sol-gel; rare earth doping; phase transition temperature; nanostructure TiO_ 2; anti-UV capacity;
D O I
10.19884/j.1672-5220.2006.05.025
中图分类号
TS190.2 [染料、颜料、药剂及助剂];
学科分类号
082103 ;
摘要
Titania sol has been prepared by the sol-gel process with Ti(OC 4 H 9 ) 4 as precursor. TiO 2 gel was obtained through hydrolysis and condensation process. Rare earth such as La 2 O 3 , CeO 2 and Gd2O3 were introduced into the nanostructure TiO 2 . After TiO 2 and rare earth doped TiO 2 powders were calcined at 400℃, 500℃, 600℃, 700℃ and 800℃ respectively, the characteristic analyses of the TiO 2 samples were studied by UV-VIS, XRD and TEM etc. It was found that there are some stronger absorption peaks at 200-325 nm. The rare earth doping can increase the phase transition temperature converting anatase phase into rutile phase, can decrease the grain size of TiO 2 particles and can improve the anti-UV capacity of the coating fabrics.
引用
收藏
页码:108 / 112
页数:5
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