Oxidative Desulfurization of Diesel Fuel with Hydrogen Peroxide Using Na2WO4 as Catalyst

被引:0
|
作者
Sun Xin
Long Jun
Xu Benjing
Xie Chaogang (Research Institute of Petroleum Processing
机构
关键词
oxidative desulfurization; dibenzothiophene; Na2WO4; hydrogen peroxide;
D O I
暂无
中图分类号
TE624.5 [];
学科分类号
081702 ;
摘要
Oxidative desulfurization was performed on Na2WO4 catalyst in the presence of hydrogen peroxide and acetic acid under mild reaction conditions (atmospheric pressure and temperature range of 293—343 K). Different organic compounds including benzothiophene (BT), dibenzothiophene (DBT), 4, 6-dimethyl dibenzothiophene (4, 6-DMDBT) were used to investigate the reactivity of this catalyst, and the effect of various parameters, such as temperature, solvents and the amount of oxidant reagent used in oxidative desulfurization reaction, was also examined. The results showed that the Na2WO4- H2O2 system was very effective for oxidative desulfurization, and the oxidation of BT, DBT and 4, 6-DMDBT was influ-enced by different parameters.
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页码:45 / 50
页数:6
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