Sulfonated carbon catalyzed oxidation of aldehydes to carboxylic acids by hydrogen peroxide

被引：0

作者：

Lipeng Zhou ^{[1
]}

Beibei Dong ^{[1
]}

Si Tang ^{[1
]}

Hong Ma ^{[1
]}

Chen Chen ^{[1
]}

Jie Xu ^{[2
]}

Xiaomei Yang ^{[1
]}

机构：

[1] College of Chemistry and Molecular Engineering,Zhengzhou University

[2] State Key Laboratory of Catalysis,Dalian National Laboratory for Clean Energy,Dalian Institute of Chemical Physics,Chinese Academy of Sciences

来源：

Journal of Energy Chemistry | 2013年 / 22卷 / 04期

关键词：

aldehyde; carboxylic acid; oxidation; hydrogen peroxide; sulfonated carbon;

D O I：

暂无

中图分类号：

O643.32 [催化反应];

学科分类号：

081705 ;

摘要：

Sulfonated carbon as a strong and stable solid acid catalyst exhibited excellent catalytic performance in various acid-catalyzed reactions. Here, sulfonated carbon, as catalyst for oxidation reaction, was prepared via the carbonization of starch followed by sulfonation with concentrated sulfuric acid. N2 physisorption, X-ray diffraction, Fourier transform infrared spectroscopy, X-ray fluorescence and acid-base titration were used to characterize the obtained materials. The catalytic activity of sulfonated carbon was studied in the oxidation of aldehydes to carboxylic acids using 30 wt% H2O2 as oxidant. This oxidation protocol works well for various aldehydes including aromatic and aliphatic aldehydes. The sulfonated carbon can be recycled for three times without obvious loss of activity.

引用

页码：659 / 664

页数：6

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