Rh doping effect on coking resistance of Ni/SBA-15 catalysts in dry reforming of methane

被引：1
|
作者：
Wen-Jia Cai [1 ]
Lin-Ping Qian [1 ]
Bin Yue [1 ]
He-Yong He [1 ]
机构：
[1] Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University
来源：
Chinese Chemical Letters | 2014年 / 25卷 / 11期
基金：
中国国家自然科学基金;
关键词：
Methane reforming Carbon dioxide Rh–Ni/SBA-15 Carbon deposition;
D O I：
暂无
中图分类号：
O643.36 [催化剂];
学科分类号：
081705 ;
摘要：
A series of SBA-15 supported bimetallic Rh–Ni catalysts with different weight ratio of Rh/Ni in the range of 0–0.04 were prepared for carbon dioxide reforming of methane. The doping effect of Rh on catalytic activity as well as carbon accumulation and removal over the catalysts was studied. The characterization results indicated that the addition of a small amount of Rh promoted the reducibility of Ni particles and decreased the Ni particle size. During the dry reforming reaction, the carbon deposition was originated from CH4 decomposition and CO disproportionation. The Rh–Ni catalyst with small metallic particle size inhibited the carbon formation and exhibited high efficiency in the removal of coke. In comparison with bare Ni-based catalyst, the Rh–Ni bimetallic catalysts showed high activity and stability in the dry reforming of methane.
引用
收藏
页码：1411 / 1415
页数：5
相关论文
共 50 条
  • [1] Rh doping effect on coking resistance of Ni/SBA-15 catalysts in dry reforming of methane
    Cai, Wen-Jia
    Qian, Lin-Ping
    Yue, Bin
    He, He-Yong
    [J]. CHINESE CHEMICAL LETTERS, 2014, 25 (11) : 1411 - 1415
  • [2] SBA-15 supported mesoporous Ni and Co catalysts with high coke resistance for dry reforming of methane
    Erdogan, Berna
    Arbag, Huseyin
    Yasyerli, Nail
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (03) : 1396 - 1405
  • [3] Dry reforming of methane over Ni/SBA-15 catalysts prepared by homogeneous precipitation method
    Zhang, Qiulin
    Wang, Jing
    Ning, Ping
    Zhang, Tengfei
    Wang, Mingzhi
    Long, Kaixian
    Huang, Jianhong
    [J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2017, 34 (11) : 2823 - 2831
  • [4] Dry reforming of methane over Ni/SBA-15 catalysts prepared by homogeneous precipitation method
    Qiulin Zhang
    Jing Wang
    Ping Ning
    Tengfei Zhang
    Mingzhi Wang
    Kaixian Long
    Jianhong Huang
    [J]. Korean Journal of Chemical Engineering, 2017, 34 : 2823 - 2831
  • [5] Influence of Lanthanide Promoters on Ni/SBA-15 Catalysts for Syngas Production by Methane Dry Reforming
    Omoregbe, Osaze
    Danh, Huong T.
    Abidin, S. Z.
    Setiabudi, H. D.
    Abdullah, Bawadi
    Vu, Khanh B.
    Vo, Dai-Viet N.
    [J]. PROCEEDING OF 4TH INTERNATIONAL CONFERENCE ON PROCESS ENGINEERING AND ADVANCED MATERIALS (ICPEAM 2016), 2016, 148 : 1388 - 1395
  • [6] Temperature hysteresis in dry reforming of methane on Ni/SBA-15 catalyst
    Wang, Shenghong
    Wang, Ye
    Zhao, Qing
    Wang, Yannan
    Hu, ChangWei
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [7] Effect of the order of Ni and Ce addition in SBA-15 on the activity in dry reforming of methane
    Kaydouh, Marie-Nour
    El Hassan, Nissrine
    Davidson, Anne
    Casale, Sandra
    El Zakhem, Henri
    Massiani, Pascale
    [J]. COMPTES RENDUS CHIMIE, 2015, 18 (03) : 293 - 301
  • [8] Rh-Ni/SBA-15 prepared by two solvents method as stable catalysts for the dry reforming of methane at high pressure
    Kaydouh, M. N.
    El Hassan, N.
    El Zakhem, H.
    Kaydouh, M. N.
    Davidson, A.
    Casale, S.
    Massiani, P.
    [J]. 2015 INTERNATIONAL MEDITERRANEAN GAS AND OIL CONFERENCE (MEDGO), 2015,
  • [9] Boron-doped Ni/SBA-15 catalysts with enhanced coke resistance and catalytic performance for dry reforming of methane
    Singh, Sharanjit
    Trinh Duy Nguyen
    Siang, Tan Ji
    Phuong, Pham T. T.
    Nguyen Huu Huy Phuc
    Quang Duc Truong
    Lam, Su Shiung
    Vo, Dai-Viet N.
    [J]. JOURNAL OF THE ENERGY INSTITUTE, 2020, 93 (01) : 31 - 42
  • [10] Catalytic performance of Samaria-promoted Ni and Co/SBA-15 catalysts for dry reforming of methane
    Taherian, Zahra
    Yousefpour, Mardali
    Tajally, Mohammad
    Khoshandam, Behnam
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (39) : 24811 - 24822
12345