The Li/LiI/(CHIy)x battery was fabricated by using fast ionic conduclor—LiI as the solid electrolyte has not been reported. The battery exhibited an open circuit voltage of 3.1~v and an initial short circuit of 7ma/cm~2. (CHIy)x can be used in the Li/I, battery as the roleof charge transfer complex. Experimental enemy density of 110Wh/kg was obtained based on the weight of (CH)x film (weight of (CH)x electrode: ca. 4mg, doping level:y=0.11).