High-throughput CALPHAD-guided design and experimental study on the development of a novel multicomponent as-cast Al-Si-Cu-Zn-Fe-Mn-Mg based alloy through the direct melting of post-consumer scrap

被引:0
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作者
Sanchez, Jon Mikel [1 ]
Galarraga, Haize [1 ]
Marquez, Itziar [2 ]
de Cortazar, Maider Garcia [1 ]
机构
[1] TECNALIA, Basque Res & Technol Alliance BRTA, Derio 48160, Spain
[2] Otua Grp, INATEC, Legutio 01170, Spain
关键词
High-throughput calculations; Secondary aluminum alloy; Circular economy; Post-consumer scrap; Fe-rich phases; CALPHAD; Recycling; MECHANICAL-PROPERTIES; INTERMETALLIC PHASES; ALUMINUM; MICROSTRUCTURE; BEHAVIOR; CRACKING; SR;
D O I
10.1016/j.jallcom.2025.178888
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present study, high-throughput CALPHAD calculations are performed to obtain the phase equilibria and solidification properties of an as-cast aluminum alloy containing Si, Cu, Fe, Zn, Mn and Mg. The appropriate alloy compositions were reversely designed to optimize the solidification interval, promote eutectic solidification of Si and Fe-rich phases, and avoid the formation of primary intermetallic compounds, and the overall reduction of other type of intermetallic compounds. The alloy was developed entirely from post-consumer scrap by two-step simple low-cost gravity casting technology that is easily scalable. To validate the CALPHAD-guided design, the microstructure and mechanical properties of the developed alloy were studied. The developed alloy successfully demonstrated the feasibility of creating alloys from post-consumer scrap that meet industry standards, using only adjusting elements, grain refiners and modifiers. Consequently, this study provides a viable approach to increase the scrap recycling rate and contributes to the industrialization of aluminum castings with a low carbon footprint.
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页数:13
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