Ring-opening metathesis polymerization of Norbornene-derived cyclic olefins using Iminomethyl-hydroxyl-ligated tungsten Complexes: Fast reaction and tunable cis/trans selectivity

被引：0

作者：

Nayab, Saira ^{[1
,2
]}

Lee, Hyosun ^{[2
]}

Lee, Sang-Ho ^{[3
]}

机构：

[1] Shaheed Benazir Bhutto Univ, Dept Chem, Sheringal Dir U 18050, Khyber Pakhtunk, Pakistan

[2] Kyungpook Natl Univ, Green Nano Mat Res Ctr, Dept Chem, 80 Daehakro, Daegu 41566, South Korea

[3] Dongguk Univ, Dept Chem & Biochem Engn, Seoul 04620, South Korea

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2025年 / 171卷

基金：

新加坡国家研究基金会;

关键词：

Tungsten complexes; X-ray structures; Cyclic olefin; Polynorbornene; IMIDO ALKYLIDENE; ROMP; MOLYBDENUM; CATALYST; POLYMERS; BEHAVIOR; MO;

D O I：

10.1016/j.inoche.2024.113580

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Highly active tungsten complexes supported by (Z)-1-(((2-hydroxyphenyl)imino)methyl)naphthalen-2-ol (LA) and (Z)-4-chloro-2-(((2-hydroxyphenyl)imino)methyl)phenol (LB) were synthesized and characterized. The ring- opening metathesis polymerization activities were assessed using i Bu 3 Al as the co-initiator at room temperature. A 100% conversion of norbornene to high-molecular-weight polynorbornene (PNB) was obtained within 10 min with tunable cis/trans selectivity of resultant polymer depending on the ligand architecture.

引用

页数：4