The Diverse Applications of Sodium <sc>l</sc> -Ascorbate as a Reducing Agent in Organic Synthesis

被引：0
|
作者：
Magalhaes, Leticia R. [1 ]
Barbosa, Euzebio G. [1 ]
Jordao, Alessandro K. [1 ]
机构：
[1] Univ Fed Rio Grande do Norte, Ctr Ciencias Saude, Dept Farm, Rua Gen Gustavo Cordeiro de Faria S-N, BR-59012570 Natal, RN, Brazil
来源：
SYNOPEN | 2025年 / 09卷 / 01期
关键词：
sodium L-ascorbate; reduction; catalysis; photocatalysis; synthesis; TRANSFER RADICAL-ADDITION; C-H; CLICK CHEMISTRY; IN-SITU; STEREOSELECTIVE-SYNTHESIS; CHEMOENZYMATIC SYNTHESIS; CONJUGATE ADDITION; HETERO-DIRADICALS; ALKYNOIC ACIDS; ARYL HALIDES;
D O I：
10.1055/s-0040-1720162
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Sodium L-ascorbate is an inexpensive and non-hazardous organic salt derived from ascorbic acid that is widely applied as a reducing agent in diverse industrial processes and occurs naturally in some plants and animals. In organic synthesis it can participate in a variety of reactions, playing different roles as a secondary or main reactant to promote a wide range of chemical transformations, being most commonly used along with metallic catalysts. This graphical review highlights some of the numerous applications of sodium ascorbate as a reactant in organic reactions.
引用
收藏
页码：105 / 130
页数：26
相关论文
共 50 条
  • [1] Synthesis of <sc>l</sc>-cyclodextrins
    Beeren, Sophie R.
    NATURE SYNTHESIS, 2024, 3 (06): : 671 - 672
  • [2] Sequencing of <sc>d</sc>/<sc>l</sc>-DNA and XNA by Templated-Synthesis
    Joshi, Saurabh
    Romanens, Patrick
    Winssinger, Nicolas
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2025, 147 (07) : 6288 - 6296
  • [3] Synthesis and application of a photocaged-<sc>l</sc>-lactate for studying the biological roles of <sc>l</sc>-lactate
    Miyazaki, Ikumi
    Tsao, Kelvin K.
    Kamijo, Yuki
    Nasu, Yusuke
    Terai, Takuya
    Campbell, Robert E.
    COMMUNICATIONS CHEMISTRY, 2025, 8 (01):
  • [4] Effects of <sc>l</sc>-arginine/<sc>l</sc>-lysine on physicochemical properties of sodium-reduced Cantonese sausage without exogenous phosphate addition
    Li, Axiang
    Liang, Huihui
    Gao, Xun
    Fan, Xiaokang
    Fang, Hongmei
    Zhou, Cunliu
    INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY, 2024, 59 (08): : 5777 - 5786
  • [5] Multi-regulated GDP-<sc>l</sc>-galactose phosphorylase calls the tune in ascorbate biosynthesis
    Baldet, Pierre
    Mori, Kentaro
    Decros, Guillaume
    Beauvoit, Bertrand
    Colombie, Sophie
    Prigent, Sylvain
    Petriacq, Pierre
    Gibon, Yves
    JOURNAL OF EXPERIMENTAL BOTANY, 2024, 75 (09) : 2631 - 2643
  • [6] Construction and Application of a Multienzyme System for Synthesis of <sc>l</sc>-malate
    Zhao, Jielin
    Li, Xiaolian
    He, Ranfeng
    Wang, Yunshan
    Wang, Ziqiang
    APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY, 2024, 196 (12) : 8965 - 8979
  • [7] Engineering galactose oxidase for efficient cascade synthesis of <sc>l</sc>-guluronic acid from <sc>d</sc>-glucose
    Wang, Qingxiu
    Liu, Weisong
    Chang, Lijing
    Zhang, Kuncheng
    Shen, Yanbing
    Zhang, Lingling
    CATALYSIS SCIENCE & TECHNOLOGY, 2024, 14 (23) : 6956 - 6967
  • [8] Manganese(<sc>iii</sc>) acetate in organic synthesis: a review of the past decade
    Wang, Jian
    Zhang, Yan
    Zhou, Ying
    Gu, Xin
    Han, Bingxu
    Ding, Xuelu
    Liang, Shuai
    ORGANIC CHEMISTRY FRONTIERS, 2024, 11 (23): : 6850 - 6917
  • [9] Recent advances in the application of calcium(<sc>ii</sc>) triflimide in organic synthesis
    Li, Haoran
    Kuang, Minyao
    Liu, Yuwei
    Yi, Wei
    Wang, Shengdong
    ORGANIC CHEMISTRY FRONTIERS, 2025, 12 (04): : 1355 - 1373
  • [10] Crystal growth, vibrational, optical, computational, photoluminescence and SHG analyses of lithium <sc>l</sc>-ascorbate dihydrate crystal
    Sathyanarayanan, R.
    Selvapandiyan, M.
    Senthilkumar, C.
    Keerthivasan, T.
    Srinivasan, M.
    JOURNAL OF MATERIALS RESEARCH, 2023, 38 (22) : 4858 - 4867
12345