Cobalt-Catalyzed Regioselective C8-H Sulfoxamination of 1-Naphthylamine Derivatives with NH-Sulfoximines

被引：0
|
作者：
Rathod, Nileshkumar B. [1 ,2 ]
Patel, Raj N. [1 ,2 ]
Patel, Sachinkumar D. [1 ,2 ]
Patel, Dharmik M. [1 ,2 ]
Sonawane, Mahesh A. [1 ,2 ]
Thakur, Dinesh Gopichand [1 ,2 ]
Ghosh, Subhash Chandra [1 ,2 ]
机构：
[1] Cent Salt & Marine Chem Res Inst CSIR, Nat Prod & Green Chem Div, Bhavnagar 364002, Gujarat, India
[2] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2024年
关键词：
FUNCTIONALIZATION; AMINE; MILD;
D O I：
10.1021/acs.joc.4c02318
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple cobalt-catalyzed, picolinamide-directed C8-H sulfoxamination of 1-naphthalamides with NH-sulfoximines has been developed. This cross-dehydrogenative C-H/N-H coupling reaction offers a facile route to N-arylated sulfoximines, exhibiting high yields, a broad substrate scope, and excellent functional group tolerance and scalability.
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页数：9
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