Selective photochemical reduction of nitroarenes to N-arylhydroxylamines with γ-terpinene

被引：0
|
作者：
Huang, Xinxin [1 ]
Cai, Chun [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Sch Chem & Chem Engn, 200 Xiaolingwei, Nanjing 210094, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2025年
关键词：
CHEMISTRY;
D O I：
10.1039/d5cc00159e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The preparation of N-arylhydroxylamines (N-AHAs) by photochemical reduction of nitroarenes has been presented. Herein, N-AHAs were obtained by selective transformation of nitroarenes under irradiation of 413 nm LEDs at room temperature. Plant-derived gamma-terpinene was employed as the hydrogen source. Notably, extra catalysts or additives are not required. This protocol exhibits broad scope of substrates, excellent tolerance of functional groups, high yields and selectivity. Moreover, successful applications of N-AHAs also demonstrate the practicality of this methodology.
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页数：4
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