We systematically assess the DUNE experiment's ability to distinguish between various beyond-standard neutrino oscillation hypotheses pair combinations. For a pair comparison, we evaluate the statistical separation, where one hypothesis plays the role of the true signal while the other corresponds to the test signal. The beyond-standard neutrino oscillation hypotheses under scrutiny include neutrino decay (invisible and visible), non-standard interactions, quantum decoherence, and the violation of the equivalence principle. We found that the violation of the equivalence principle is the easiest to differentiate compared to the rest of the hypotheses. Additionally, from our x2 statistical separation test, we investigate potential discrepancies between the measured CP-violation phase SAP, 623, and Delta m231 relative to their respective true values, which could occur for a given comparison. In our analysis, we will take the true values of SAP as 90 degrees and 180 degrees, while 623 and Delta m231 are fixed in its global fit values. In particular, even in cases where the scenarios of beyond-standard neutrino oscillation hypotheses are statistically indistinguishable, the measured values can exhibit significant deviations from their true values.