Electrically charged flows were investigated using experimental techniques. These flows were visualized and recorded employing high-speed video, which allowed the study of the formation of electrically charged filaments, focusing on the flow characteristics at meniscus rupture and the flow downstream of the atomization region. Experiments were performed following the design-of-experiments methodology, which provided information on the effect of the main factors and their combinations on the response variables, such as spray angle, size distribution, and particle number. Meniscus formation and its rupture were analyzed as a function of competition between forces. Furthermore, the different rupture modes were determined as a function of the electric field intensity (electric Bond number, Boe). The findings reveal that the best atomization condition is defined by a stable Taylor cone jet (at meniscus rupture). However, the results differ downstream of the atomization, since stable jet atomization is characterized by poor particle dispersion. To improve such conditions, it was found that flows with oscillation around the vertical axis and particle detachment (controlled instability) lead to better atomization. This is because a greater dissemination of particles is promoted, and greater homogeneity of the product and smaller particle sizes are generated. A secondary atomization process causes such conditions after the rupture of the meniscus, which is known as Coulomb fission.