Compositional evolution (Li, Be) in cordierite-group minerals from metamorphic and magmatic rocks of the Bory Granulite Massif, Moldanubian Zone, Czech Republic and its implications for origin of related granitic pegmatites

被引:0
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作者
Hreus, S. [1 ,2 ]
Kocab, J. [2 ]
Novak, M. [2 ]
Galiova, M. Vasinova [3 ]
Gadas, P. [2 ]
机构
[1] Tech Univ Kosice, Inst Geosci, Kosice 04200, Slovakia
[2] Masaryk Univ, Dept Geol Sci, Brno 61137, Czech Republic
[3] Brno Univ Technol, Inst Chem & Technol Environm Protect, Brno 61200, Czech Republic
关键词
Cordierite; Sekaninaite; EPMA; LA-ICP-MS; Compositional trends; Granulite; Migmatite; Pegmatite; BOHEMIAN MASSIF; DOLNI BORY; SECONDARY BERYL; OXIDE MINERALS; VARISCAN BELT; TOURMALINE; ELEMENT; SYSTEM; SEKANINAITE; LITHIUM;
D O I
10.1016/j.chemgeo.2025.122668
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
Samples of cordierite-group minerals (CGM) from various rocks in the Bory Granulite Massif (BGM), Moldanubian Zone - granulite (1), leucosome to pegmatitic leucosome in migmatites (2), small zoned granitic pegmatites (2) and large, complexly zoned granitic pegmatites (11) were examined by the means of EPMA and LA-ICP-MS. CGM are morphologically and compositionally highly variable from subhedral grains, similar to 0.5-5 cm in size, of cordierite (XMg57) from granulite, subhedral grains, < similar to 5 cm, of cordierite-sekaninaite (XMg56-44) from leucosome to pegmatitic leucosome, cordierite (XMg60) from graphic unit and subhedral grains to large conic subhedral crystals, up to 0.7 m long, of sekaninaite (XMg28-3) mainly from albite unit of complexly zoned pegmatites. Concentrations of Be and chiefly Li in CGM vary significantly - granulite (Be = 84-89 ppm, Li = 204-242 ppm), leucosome to pegmatitic leucosome (Be = 184-317 ppm, Li = 204-338 ppm), complexly zoned pegmatites (outer and blocky units - Be =150-200, Li = 577-904 ppm; albite unit - Be <= 51 ppm, Li = 572-3662 ppm; <= 0.79 wt% Li2O). The following substitution mechanisms were revealed: homovalent R2+ substitutions - major Mg = Fe in all types of CGM, minor Mg + Fe = Mn in sekaninaite with low XMg, moderate to minor heterovalent substitution NaLi = square R(2+)and insignificant substitution NaAl = square Si in sekaninaite from complexly zoned pegmatites. Textural evolution from small bodies of leucosome to large complexly zoned pegmatites with Li-rich sekaninaite, and to Li-rich lepidolite pegmatites in BGM somewhat resembles evolution of simple anatectic pegmatites to albite-spodumene pegmatites from the Austroalpine Unit Pegmatite Province (Eastern European Alps); however, pegmatites from BGM with Li-bearing sekaninaite and lepidolite + petalite crystallized at lower P similar to 2 kbar. Variations in concentrations of Be and Li in the individual paragenetic types of CGM and chiefly high Li and very low Be in sekaninaite manifest that pegmatitic melts underwent several steps of magmatic fractionation evident chiefly in complexly zoned pegmatites.
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页数:13
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