Highly efficient synthesis of mononuclear Pt-based carboxylic complexes trans-[Py 2 Pt(OC(O)R) 2 ] (R = Me, But, Ph)

被引：1
|
作者：
Panina, Maria V. [1 ,2 ]
Ogarkova, Nadezhda K. [1 ,3 ]
Dorovatovskii, Pavel V. [4 ]
Sulimova, Olesya V. [1 ,2 ]
Sosunov, Egor A. [1 ,2 ]
Cherkashina, Natalia V. [1 ]
Makarevich, Julia E. [1 ,2 ]
Navasardyan, Mger A. [1 ]
Popova, Anna S. [1 ]
Yakushev, Ilya A. [1 ]
机构：
[1] Russian Acad Sci, N S Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
[2] D I Mendeleev Univ Chem Technol Russia, Russian Acad Sci, Higher Chem Coll, Moscow 125047, Russia
[3] Peoples Friendship Univ Russia, RUDN Univ, Moscow 117198, Russia
[4] Kurchatov Inst, Natl Res Ctr, Moscow 123182, Russia
来源：
MENDELEEV COMMUNICATIONS | 2024年 / 34卷 / 06期
关键词：
platinum; synthesis; carboxylate complexes; pyridine; RAY CRYSTAL-STRUCTURE; HETEROMETALLIC PALLADIUM; PLATINUM; ACETATE; HYDROLYSIS; BONDS; METAL;
D O I：
10.1016/j.mencom.2024.10.013
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two novel synthetic routes were suggested for square-planar carboxylic platinum(ii) complexes with acetic, pivalic, and benzoic ligands. In the first method, heating ionic complex [Py4Pt](OAc)2 under reduced pressure gives a molecular compound trans-[Py2Pt(OAc)2] with a moderate yield. In the second method, the same starting compound [Py4Pt](OAc)2 <middle dot> 6 H2O is melted with pivalic or benzoic acids, which leads to analogous carboxylic trans-complexes with almost quantitative yields.
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页码：808 / 811
页数：4
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