Synthesis of explosive peroxides using unrecognised explosive precursors- percarbonates and perborates

被引：4

作者：

Pawlus, Klaudia ^{[1
]}

Kwiatkowski, Mateusz ^{[1
,2
]}

Stolarczyk, Agnieszka ^{[1
]}

Glosz, Karolina ^{[1
]}

Jarosz, Tomasz ^{[1
]}

机构：

[1] Silesian Tech Univ, Fac Chem, Ks M Strzody 9 St, PL-44100 Gliwice, Poland

[2] Silesian Tech Univ, Fac Chem, Ks M Strzody 9 St, PL-44100 Gliwice, Poland

来源：

FIREPHYSCHEM | 2022年 / 2卷 / 03期

关键词：

Explosive precursor; Explosive peroxide; HMTD; Hexamethylene triperoxide diamine; TATP; Acetone peroxide; Synthesis; Perborate; Percarbonate; HEXAMETHYLENE TRIPEROXIDE DIAMINE; TRIACETONE TRIPEROXIDE; SODIUM PERCARBONATE; HYDROGEN-PEROXIDE; TATP; CONFORMERS; HEADSPACE; DENSITY; ACETONE;

D O I：

10.1016/j.fpc.2022.06.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The paper reports the synthesis of an explosive peroxide using sodium perborate (SPB) and sodium percarbonate (SPC) as alternatives to hydrogen peroxide, a well-known explosives precursor. It has been reported that the oxidising agents used in the synthesis can replace hydrogen peroxide in some reactions. Consequently, we tried to assess the threat of using those substances being used for the unlawful manufacture of explosive peroxides. We have found that both SPB and SPC, allow producing the explosive peroxides with good yields and purity, as confirmed by 1 H NMR and IR spectroscopy, as well as by HPLC and controlled burning experiments.

引用

页码：285 / 293

页数：9

共 22 条

[1] Detection of Explosive Precursors Using Low-Field Magnetic Resonance Imaging
Krylatykh, Natalya A.
Fattakhov, Yakh'ya V.
Fakhrutdinov, Albert R.
Anashkin, Vladimir N.
Shagalov, Valeriy A.
Khabipov, Ramil Sh.
APPLIED MAGNETIC RESONANCE, 2016, 47 (08) : 915 - 924
[2] Recognition of Explosive Precursors Using Nanowire Sensor Array and Decision Tree Learning
Cho, Junghwan
Li, Xiaopeng
Gu, Zhiyong
Kurup, Pradeep U.
IEEE SENSORS JOURNAL, 2012, 12 (07) : 2384 - 2391
[3] Detection of Explosive Precursors Using Low-Field Magnetic Resonance Imaging
Natalya A. Krylatykh
Yakh’ya V. Fattakhov
Albert R. Fakhrutdinov
Vladimir N. Anashkin
Valeriy A. Shagalov
Ramil Sh. Khabipov
Applied Magnetic Resonance, 2016, 47 : 915 - 924
[4] Classification and concentration estimation of explosive precursors using nanowires sensor array and decision tree learning
Cho, Junghwan
Li, Xiaopeng
Gu, Zhiyong
Kurup, Pradeep
OLFACTION AND ELECTRONIC NOSE: PROCEEDINGS OF THE 14TH INTERNATIONAL SYMPOSIUM ON OLFACTION AND ELECTRONIC NOSE, 2011, 1362 : 60 - +
[5] PLASMOCHEMICAL SYNTHESIS AT HIGH-PRESSURE USING AN EXPLOSIVE SOURCE OF PLASMA
VOITENKO, AE
KIRKO, VI
COMBUSTION EXPLOSION AND SHOCK WAVES, 1978, 14 (01) : 77 - 81
[6] Synthesis and characteristic of carbon-encapsulated ferronickel nanoparticles by detonation decomposition of doping with nitrate explosive precursors
Luo Ning
Li Xiaojie
Sun Yuling
Wang Xiaohong
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 505 (01) : 352 - 356
[7] Advanced materials synthesis and microstructural characterization using explosive at Sojo University
Li, Seiichiro
Kira, Akio
Tomoshige, Ryuichi
Fujita, Masahiro
EXPLOSION, SHOCK WAVE AND HYPERVELOCITY PHENOMENA IN MATERIALS II, 2008, 566 : 321 - +
[8] A Safer Synthesis of the Explosive Precursors 4-Aminofurazan-3-Carboxylic Acid and its Ethyl Ester Derivative
Miller, Christopher W.
Johnson, Eric C.
Sausa, Rosario C.
Orlicki, Joshua A.
Sabatini, Jesse J.
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2020, 24 (04) : 599 - 603
[9] δ13C analysis to screen out explosive precursors by using cavity ring down laser spectroscopy
Rizzo, A.
Telloli, C.
Bartolomei, P.
Manassero, F.
EUROPEAN PHYSICAL JOURNAL PLUS, 2018, 133 (07):
[10] Explosive compaction and synthesis of MgB2 superconductor using the powder in tube technique
Mamalis, A. G.
Hristoforou, E.
Manolakos, D. E.
Svec, P.
Prikhna, T.
Theodorakopoulos, J. D.
Kouzilos, G.
JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 2008, 10 (05): : 1000 - 1004

← 1 2 3 →