Room-temperature phosphorescence in crystalline bifurcating halogen⋯halogen synthon containing chromophore

被引：0
|
作者：
Sujilkumar, Suvarna [1 ]
Kalyani, Agaja [1 ]
Hariharan, Mahesh [1 ]
机构：
[1] Indian Inst Sci Educ & Res Thiruvananthapuram, Sch Chem, Maruthamala PO, Thiruvananthapuram 695551, Kerala, India
来源：
CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 29期
关键词：
SUPRAMOLECULAR SYNTHONS; PERTURBATION-THEORY;
D O I：
10.1039/d5cc00496a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein, we report room-temperature phosphorescence in a brominated dihydropentacene derivative having bifurcating bromine synthon in the crystalline state. Delayed emission experiments and insights from theoretical investigations have corroborated the feasibility of long-lived triplet excitons, offering promising implications for synthon-stabilized, metal-free, organic phosphors.
引用
收藏
页码：5463 / 5466
页数：4
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