Coupling CO2 Electroreduction to CO with alkyne Alkoxycarbonylation

被引：0

作者：

Shi, Haonan ^{[1
]}

Jia, Shuaiqiang ^{[2
]}

Dong, Mengke ^{[2
]}

Wu, Haihong ^{[1
]}

Huang, Zheng ^{[1
,3
]}

Dong, Kaiwu ^{[1
,3
]}

机构：

[1] East China Normal Univ, Sch Chem & Mol Engn, State Key Lab Petr Mol & Proc Engn, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

[2] East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

[3] East China Normal Univ, Chang Kung Chuang Inst, Sch Chem & Mol Engn, Shanghai 200241, Peoples R China

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 42期

基金：

国家重点研发计划;

关键词：

CARBONYLATION; CONVERSION; ELECTROCATALYSTS; ALKENES;

D O I：

10.1021/acs.orglett.4c02431

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The alkyne alkoxycarbonylation to alpha- or beta-substituted acrylates was coupled with the electrocatalytic reduction of CO2 to CO. The CO-enriched gaseous mixture produced from the electrocatalytic reduction of CO2 was collected and directly used in the alkyne alkoxycarbonylation. The CO content was found to be critical to the process of carbonylation, and satisfying results were attained by using the gas mixture containing >15 vol % CO. This method offered an efficient but simple CO source from CO2 electroreduction to the alkoxycarbonylation reaction in two-compartment manner.

引用

页码：8982 / 8987

页数：6

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