Research progress on design, synthesis and performance of energetic polynitro hexaazaisowurtzitane derivatives: Towards improved CL-20 analogues

被引:4
|
作者
Parakhin, Vladimir V. [1 ]
Smirnov, Gennady A. [1 ]
机构
[1] Russian Acad Sci, N D Zelinsky Inst Organ Chem, Leninsky Prosp 47, Moscow 119991, Russia
来源
FIREPHYSCHEM | 2024年 / 4卷 / 01期
关键词
Energetic materials; Cage compounds; Polynitro hexaazaisowurtzitanes; Energetic functionalization; Structure-property relationship; THERMAL-DECOMPOSITION; PROTECTING GROUP; SENSITIVITY; TRIFLUOROACETYL; MOLECULES; AMINES; MONO; DI;
D O I
10.1016/j.fpc.2023.05.006
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In order to discover of high-energy materials with characteristics that surpass modern benchmarks, it is necessary to study the widest range of potential structures. The design of energetic compounds using high-nitrogen cage scaffolds provides new opportunities. One of the promising representatives of polycyclic multinitragen cages is the hexaazaisowurtzitane, since the most powerful explosive CL-20 is based on it. In recent years, the synthesis of CL-20 analogues has been actively developed. This review presents progress in the synthesis, performance and study of the structure-property relationship for energetic polynitro hexaazaisowurtzitanes over the past decade.
引用
收藏
页码:21 / 33
页数:13
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