Recent advances of MXene@MOF composites for catalytic water splitting and wastewater treatment approaches

被引：12

作者：

Afzal, Samreen ^{[1
]}

Rehman, Aziz ur ^{[1
]}

Najam, Tayyaba ^{[2
]}

Hossain, Ismail ^{[3
]}

Abdelmotaleb, Mostafa A.I. ^{[4
]}

Riaz, Sundas ^{[1
]}

Karim, Md Rezaul ^{[5
]}

Shah, Syed Shoaib Ahmad ^{[6
]}

Nazir, Muhammad Altaf ^{[1
]}

机构：

[1] Institute of Chemistry, The Islamia University of Bahawalpur, Bahawalpur,63100, Pakistan

[2] Research and Development Division, SciTech International Pvt Ltd, G-10/1 Islamabad, Pakistan

[3] Department of Nuclear and Renewable Energy, Ural Federal University, Yekaterinburg,620002, Russia

[4] Research Center for Advanced Materials Science (RCAMS), Chemistry Department, Faculty of Science, King Khalid University, P.O. Box 9004, Abha,61413, Saudi Arabia

[5] School of Chemical Engineering, Yeungnam University, 280 Daehak-ro, Gyeongbuk, Gyeongsan,38541, Korea, Republic of

[6] Department of Chemistry, School of Natural Sciences, National University of Sciences and Technology, Islamabad,44000, Pakistan

来源：

Chemosphere | 2024年 / 364卷

关键词：

MXenes are a group of 2D material which have been derived from the layered transition metal nitrides and carbides and have the characteristics like electrical conductivity; high surface area and variable surface chemical composition. Self-assembly of clusters/metal ions and organic linkers forms metal organic framework (MOF). Their advantages of ultrahigh porosity; highly exposed active sites and many pore architectures have garnered them a lot of attention. But poor conductivity and instability plague several conventional MOF. To address the issue; MOF can be linked with MXenes that have rich surface functional groups and excellent electrical conductivity. In this review; different etching methods for exfoliation of MXene along with the synthesis methods of MXene/MOF composites are reviewed; including hydrothermal method; solvothermal method; in-situ growth method; and self-assembly method. Moreover; application of these MXene/MOF composites for catalytic water splitting and wastewater treatment were also discussed in details. In addition to increasing a single MOF conductivity and stability; MXenes can add a variety of new features; such the template effect. Due to these benefits; MXene/MOF composites can be effectively used in several applications; including photocatalytic/electrocatalytic water splitting; adsorption and degradation of pollutants from wastewater. Finally; the authors explored the current challenges and the future opportunities to improve the efficiency of MXene/MOF composites. © 2024;

D O I：

10.1016/j.chemosphere.2024.143194

中图分类号：

学科分类号：

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