To determine the geological age, petrogenesis, and tectonic setting of Mesozoic volcanic rocks in the Ningyuancun Formation in Xunke area, Lesser Hinggan Range, the zircon U-Pb geochronology, petrographic observations, and geochemical analyses of major and trace elements were conducted in this study. Zircon U-Pb dating showed that the volcanic rocks of the Ningyuancun Formation were formed in the Early Cretaceous(112.97±0.90 Ma). Major element analyses revealed that the content of SiO2 weighted from 74.14% to 76.54%,indicating the volcanic rocks to be high-silica and felsic. The content of Al2O3 varies from 12.48% to 13.65%.A total alkali content of the volcanic rocks range between 8.46% and 9.56%, with Na2O/K2O ratios from 0.69 to 0.89. This indicated that the volcanic rocks belonged to a highly differentiated calc-alkaline series. Additionally,A/CNK values range from 0.950 to 1.015, and A/NK values vary between 0.999 and 1.127, suggesting a peraluminous characteristic. Trace element analysis showed a right-sloping “V-shaped” REE pattern, with the enrichment in light REEs and a prominent negative anomaly of Eu. The volcanic rocks are enriched in Rb,Th, U, La, and Ce, while Ba, Sr, and Ti are depleted. Rb/Sr ratio ranges from 10.01 to 12.46, Ti/Y ratio is from 51.14 to 95.72, and Ti/Zr ratio is from 5.78 to 6.41. It is suggested that the magma was derived from the partial melting of crustal rocks. This evidenced that the Early Cretaceous high-silica rhyolites were formed in an intracontinental extension in eastern Northeast China during the northwestward subduction of the Pacific Plate. The crustal extension, asthenospheric mantle upwelling and underplating of mantle-derived magmas resulted in the residual crystalline mush in Early Cretaceous mafic magma chambers to erupt.