Chemistry under extreme conditions: Pressure evolution of chemical bonding and structure in dense solids

Recent advances in high-pressure technologies and large-scale experimental and computational facilities have enabled scientists, at an unprecedented rate, to discover and predict novel states and materials under the extreme pressure-temperature conditions found in deep,giant-planet interiors. Based on a well-documented body of work in this field of high-pressure research, we elucidate the fundamental principles that govern the chemistry of dense solids under extreme conditions. These include:(i) the pressure-induced evolution of chemical bonding and structure of molecular solids to extended covalent solids, ionic solids and, ultimately, metallic solids, as pressure increases to the terapascal regime;(ii) novel properties and complex transition mechanisms, arising from the subtle balance between electron hybridization(bonding) and electrostatic interaction(packing) in densely packed solids; and(iii) new dense framework solids with high energy densities, and with tunable properties and stabilities under ambient conditions. Examples are taken primarily from low-Z molecular systems that have scientific implications for giant-planet models, condensed materials physics, and solid-state core-electron chemistry.