SPECTRAL DEPENDENCES OF THE ABSOLUTE QUANTUM YIELDS OF I(2P one-half ) AND I(2P3/2) ATOMS IN PHOTOLYSIS OF ORGANIC IODIDES - 2. CF3I, C2F5I, C3F7I, CF3CFICF3, AND CF3OCF2CF2I.

被引:17
|
作者
Ivanov, V.S.
Kozlov, A.S.
Pravilov, A.M.
Smirnov, E.P.
机构
来源
Soviet journal of quantum electronics | 1980年 / 10卷 / 05期
关键词
D O I
10.1070/QE1980v010n05ABEH010150
中图分类号
TN2 [光电子技术、激光技术];
学科分类号
0803 ; 080401 ; 080901 ;
摘要
A description and justification is presented of a technique for measuring the spectral dependences of the absolute quantum yields of iodine atoms in the **2P// one-half and **2P//3/////2 states in photolysis of RI organic iodides. Data are presented and interpreted for RI equals CF//3I, C//2F//5I, CF//3CFICF//3, C//3F//7I, and CF//3OCF//2CF//2I. The proposed model is checked by means of calculations of the electron density distribution in RI.
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页码:566 / 573
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