Properties and dynamics of the σ(M′-Re) π* excited state of photoreactive dinuclear LnM′-Re(CO) 3 (α-diimine) (LnM′ = Ph3Sn, (CO)5Mn, (CO)5Re; α-diimine = bpy′, iPr-PyCa, iPr-DAB) complexes studied by time-resolved emission and absorption spectroscopies

被引：0

作者：

Rossenaar, Brenda D. ^{[1
]}

Lindsay, Elspeth ^{[2
]}

Stufkens, Derk J. ^{[1
]}

Vlček Jr., Antonín ^{[3
]}

机构：

[1] Anorganisch Chemisch Laboratorium, J.H. Van't Hoff Research Institute, Universiteit Van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, Netherlands

[2] Department of Chemistry, California State University, Chico, CA 95929, United States

[3] J. Heyrovsky Inst. of Phys. Chem., Acad. of Sci. of the Czech Republic, Dolejškova 3, 182 23 Prague, Czech Republic

来源：

Inorganica Chimica Acta | 1996年 / 250卷 / 1-2 PART I期

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摘要：

引用

页码：5 / 14

共 8 条

[1] Properties and dynamics of the sigma(M'-Re)pi* excited state of photoreactive dinuclear L(n)M'-Re(CO)(3)(alpha-diimine) (L(n)M'=Ph(3)Sn, (CO)(5)Mn, (CO)(5)Re; alpha-diimine=bpy', iPr-PyCa, iPr-DAB) complexes studied by time-resolved emission and absorption spectroscopies
Rossenaar, BD
Lindsay, E
Stufkens, DJ
Vlcek, A
INORGANICA CHIMICA ACTA, 1996, 250 (1-2) : 5 - 14
[2] Halide-dependent change of the lowest-excited-state character from MLCT to XLCT for the complexes Re(X)(CO)(3)(alpha-diimine) (X=Cl, Br, I; alpha-diimine equals bpy, iPr-PyCa, iPr-DAB) studied by resonance Raman, time-resolved absorption, and emission spectroscopy
Rossenaar, BD
Stufkens, DJ
Vlcek, A
INORGANIC CHEMISTRY, 1996, 35 (10) : 2902 - 2909
[3] First direct structural information on a reactive σπ* excited state: Time-resolved UV-Vis and IR spectroscopic study of Re(benzyl)(CO)3(iPr-DAB)
Rossenaar, Brenda D.
George, Michael W.
Johnson, Frank P.A.
Stufkens, Derk J.
Turner, James J.
Vivek, Antonin Jr.
Journal of the American Chemical Society, 1995, 117 (46)
[4] sigma-pi* electronic transition of the di- and trinuclear complexes Ru(E)(E')(CO)(2)(iPr-DAB): Resonance Raman, electronic absorption, emission, and density functional study (E=Me, SnPh3, M(CO)(5); E'=M(CO)(5); M=Mn, Re; iPr-DAB=N,N'-diisopropyl-1,4-diaza-1,3-butadiene)
Aarnts, MP
Wilms, MP
Stufkens, DJ
Baerends, EJ
Vlcek, A
ORGANOMETALLICS, 1997, 16 (10) : 2055 - 2062
[5] FIRST DIRECT STRUCTURAL INFORMATION ON A REACTIVE SIGMA-PI-ASTERISK EXCITED-STATE - TIME-RESOLVED UV-VIS AND IR SPECTROSCOPIC STUDY OF RE(BENZYL)(CO)(3)(IPR-DAB)
ROSSENAAR, BD
GEORGE, MW
JOHNSON, FPA
STUFKENS, DJ
TURNER, JJ
VLCEK, AJR
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (46) : 11582 - 11583
[6] Photoinduced radical formation from the complexes [Re(R)(CO)3(4,4′-Me2-bpy)] (R = CH3, CD3, Et, iPr, Bz):: A nanosecond time-resolved emission, UV-Vis and IR absorption, and FT-EPR study
Kleverlaan, CJ
Stufkens, DJ
Clark, IP
George, MW
Turner, JJ
Martino, DM
van Willigen, H
Vlcek, A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (42) : 10871 - 10879
[7] SPECTROSCOPIC (IR, UV-VIS, H-1 AND SN-119 NMR, RESONANCE RAMAN) PROPERTIES OF [(C6H5)3EM(CO)3(ALPHA-DIIMINE)] (M = MN, E = GE, SN, PB, M = RE, E = SN) COMPLEXES AND X-RAY STRUCTURE OF [(C6H5)3SNMN(CO)3(TERT-BU-DAB)]
ANDREA, RR
DELANGE, WGJ
STUFKENS, DJ
OSKAM, A
INORGANICA CHIMICA ACTA, 1988, 149 (01) : 77 - 84
[8] Excited states of nitro-polypyridine metal complexes and their ultrafast decay.: Time-resolved IR absorption, spectroelectrochemistry, and TD-DFT calculations of fac-[Re(Cl)(CO)3(5-nitro-1,10-phenanthroline)]
Gabrielsson, A
Matousek, P
Towrie, M
Hartl, F
Zális, S
Vlcek, A
JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (28): : 6147 - 6153

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