HOMOGENEOUS ELECTRON TRANSFER PROCESSES.

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作者：
German, E.D.
Dvali, V.G.
Dogonadze, R.R.
Kuznetsov, A.M.
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Soviet Electrochemistry (English Translation of Elektro-Khimiia) | 1976年 / 12卷 / 05期
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摘要：
The reaction rate constants of electron transfer between the octahedral aquo complexes of a number of transition metals are calculated quantum mechanically under the assumption that the attending deformation of the coordination sphere is symmetric. It is concluded from an analysis performed in the classical approximation for the metal-ligand vibrational frequencies that quantum effects are insignificant in the complexes being discussed. The results of numerical calculations are compared with experiment.
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页码：639 / 643
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