Preparation and properties of super absorbent composite resin

被引:0
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作者
Zhang, Lan [1 ,2 ]
Yin, Yansheng [1 ,2 ]
Long, Fei [3 ]
Yang, Rongxing [3 ]
机构
[1] Laboratory for Liquid Structure and Heredity, Shandong University, Jinan 250061, China
[2] Engineering Ceramics Laboratory, Shandong University, Jinan 250061, China
[3] Department of Material and Chemical Engineering, Guilin University of Technology, Guilin 541004, China
关键词
Bentonite - Copolymerization - Crosslinking - Degradation - Initiators (chemical) - Water absorption - X ray diffraction analysis;
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中图分类号
学科分类号
摘要
One new type of super absorbent composite resin that can be self-degraded was prepared by using a new crosslink reagent. It was prepared by water solution co-polymerization based on acrylamide, acrylic acid, ammonium persulfat, bentonite and pillared bentonite. Ammonium persulfat was the initiator and polyhydroxyl-Al cations which was in bentonite layers was the crosslink reagent. The pillared effect of bentonite was studied by X-ray diffraction analysis; the best dosage of pillared bentonite and initiator was studied by researching the absorption capability of distilled water and 0.9% salt solution, respectively. The self-degradation of composite resin was studied by observing the state of the composite resin gel. The pillared effect was very good. The polyhydroxyl-Al cations was introduced into the layer of bentonite. The best dosage of pillared bentonite and initiator was 2.4% and 0.34% of total monomer quality, respectively. The self-degradation of this composite resin was better than that of other super absorbent rein, At 65°C it was self-degraded completely in 25 days.
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页码:2009 / 2013
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