Theoretical considerations of sodium nitrite oxidation and fine grinding in refractory precious-metal concentrate pressure leaching

Since 1984, nitrogen-species catalyzed pressure leaching has been utilized at Sunshine Mining and Refining Company for the recovery of precious metals from a refractory sulfide concentrate. The process operates without the use of cyanide. The plant is now the only industrial-scale commercial application of this technology. Since the inception of the process, changes have been implemented to improve efficiencies and throughputs. Two of these changes, the replacement of nitric acid by sodium nitrite and a concentrate regrind, have recently been implemented. This paper discusses the development and potential mechanisms involved in these recently patented plant-process changes. A companion publication (Anderson et al., 1996) covers the plant integration and potential applicability of the technology.