Abnormal oxidation behavior of β-NiAl base aluminide coating on a nickel-base superalloy

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作者
Xiaofeng, Sun [1 ]
Hengrong, Guan [1 ]
Tao, Jin [1 ]
Taofeng, An [1 ]
Zhuangqi, Hu [1 ]
机构
[1] Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110015, China
关键词
Diffusion coatings - High temperature operations - Morphology - Oxidation - Phase transitions - Reaction kinetics - Scanning electron microscopy - Superalloys - Surface structure - Thermogravimetric analysis - X ray diffraction analysis;
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摘要
Isothermal oxidation of β-NiAl base aluminide coating has been studied by TGA, XRD, and SEM over the temperature range of 800-1050°C. During the initial period of oxidation, γ-Al2O3 and θ-Al2O3 were growing at a relatively high rate. Then these metastable oxides transformed to stable α-Al2O3 accompanied by a distinct decrease of the Kp values by one or two orders of magnitude at 800-1000°C. This transformation also resulted in a dramatic change in the surface morphology of the scales from blade-like oxides to equiaxed grain oxides. The higher the temperature, the faster the transformation.
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页码:734 / 739
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