STUDY OF VAPOR-LIQUID EQUILIBRIUM OF N-METHYLPYRROLIDONE-WATER BINARY SYSTEM BY AN EBULLIOMETER.

被引:0
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作者
Li, Jing-qing [1 ]
Bao, Qi [1 ]
Tian, Yi-ling [1 ]
机构
[1] Tianjin Univ, Dep of Chemistry, China, Tianjin Univ, Dep of Chemistry, China
关键词
MEASUREMENTS; -; Equipment; THERMODYNAMICS; Measurements; VAPORS;
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摘要
This paper describes the measurement of the equilibrious liquid composition and boiling points of N-methylpyrrolidone-water binary system at 760 mmHg (101. 325 kPa) with a modified Washburn ebulliometer. The parameters of interaction energy of Wilson's model were calculated by the simplex fitting method and therefore the equilibrious vapor composition of this system was determined. Then the vapor composition of this system was measured directly at 760 mmHg with a modified Rose still. The results obtained are in agreement with the calculated vapor.
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页码:107 / 115
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