Calcium Arsenates as a Form of Arsenic-Containing Waste Products.

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作者
Petrov, A.N.
Charnyi, V.Z.
Tel'nykh, T.F.
Popova, G.N.
Potapov, V.A.
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ARSENIC COMPOUNDS - INDUSTRIAL POISONS - WATER POLLUTION - Control;
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The existence in the Ca//2As//2O//7-CaO system of two intermediate compounds with the compositions Ca//3As//2O//8 and Ca//4As//2O//9, which melt incongruently at 1500 and 1550 degree C, respectively, is demonstrated. A study is made of the solubility of the individual components of the Ca//2As//2O//7-CaO system and mixtures of them in water. It is shown that the solubility of calcium arsenate with the composition Ca//4As//2O//9 is low (0. 03 mg As per liter), and this suggests a possiblity of using it for the binding and safe storage of arsenic-containing wastes from nonferrous metallurgical plants.
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页码:152 / 154
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