Densities and viscosities for correlative system of dimethyl carbonate at different temperatures

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作者
Li, Nan-Nan [1 ]
Ma, Pei-Sheng [1 ]
Jin, Hui-Yi [1 ]
Yang, Chang-Sheng [1 ]
机构
[1] Lab. for Green Chem. Technol., Sch. of Chem. Eng. and Technol., Tianjin Univ., Tianjin 300072, China
关键词
Binary mixtures - Density (specific gravity) - Methanol - Viscometers - Viscosity;
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摘要
Densities and viscosities of the binary mixture of (dimethyl carbonate + methanol) at the temperatures interval (293.15-323.15 K) and of (dimethyl carbonate + chlorobenzene) at the temperatures interval (293.15-343.15 K) were determined under atmospheric pressure by using a vibrating U-shaped sample tube densimeter and Ubbelohde suspended-level viscometer. Density values gotten were used in the calculation of excess molar volumes and the gotten viscosities were used for the calculation of the viscosity deviations. For (DMC + methanol) system, the excess molar volumes and the deviations of viscosity are all negative and for (DMC + chlorobenzene) system, the excess molar volumes are positive and the deviations of viscosity are in the vicinity of zero. Excess molar volumes and deviations of viscosity were correlated with Redlich-Kister equation respectively. The standard deviations were lower than 5%. The results show these two systems can be regressed by using R-K equation.
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页码:766 / 772
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