Strontium metasilicate, SrSiO3

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作者
Nishi, Fumito [1 ]
机构
[1] Saitama Inst of Technology, Saitama, Japan
关键词
Crystal lattices - Crystal symmetry - Silicon compounds - Synthesis (chemical);
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摘要
Strontium silicon trioxide has been synthesized for the first time and its structure solved. It is isostructural with the germanium analogue SrGeO3 reported by Hilmer [Sov. Phys. Crystallogr. (1963), 7, 573-576], but the true symmetry is monoclinic, rather than hexagonal as reported earlier. The structure has alternate layers of ternary rings of SiO4 groups and close-packed Sr atoms stacked along [001]. Viewed as a polytype, this compound has a six-layer structure and the calcium analogue α-CaSiO3 [Yamanaka & Mori (1981). Acta Cryst. B37, 1010-1017] has a four-layer structure.
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页码:534 / 536
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