Synthesis and physicochemical investigation of germanium (IV) complexes with salicyl aldehyde NH2-substituted benzoyl hydrazones

被引：0

作者：

Shmatkova, N.V. ^{[1
]}

Sejrullina, I.I. ^{[1
]}

Tkachenko, V.N. ^{[1
]}

机构：

[1] Odesskij Natsional'nyj Univ. im. I.I. Mechnikova, Odessa, Ukraine

来源：

Ukrainskij Khimicheskij Zhurnal | 2005年 / 71卷 / 1-2期

关键词：

Aldehydes - Aromatic compounds - Crystal structure - Germanium compounds - Infrared spectroscopy - Mass spectrometry - Organometallics - Thermogravimetric analysis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The complexes [Ge(R-Bs&middotHCl)2] (R = 2- (I), 3- (II), 4- (III) have been obtained by interaction of GeCl4 with salicyl aldehyde N-[R-benzoyl]-hydrazone (r-H2Bs, were R = 2-, 3-, 4-NH2-; H2Bs - C6H4-CO-NH-NCH-C6H4OH) in methanol. The complex [Ge(2-NH2-Bs)2] (IV) has been synthesized by boiling of I in H2O. Their physicochemical characteristics were obtained by mass spectrometry, TGA, IR, 1H NMR spectroscopy methods. It has been stated that the complexes I-IV have octahedral configuration. Their coordination polyhedron is formed by nitrogen atom of the azomethine group and oxygen atoms of oxyazine, and oxy group.

引用

页码：23 / 27

共 50 条

[1] Organotin(IV) Complexes with 2-Acetylpyridine Benzoyl Hydrazones: Antimicrobial Activity
Despaigne, Angel A. R.
Vieira, Lorena F.
Mendes, Isolda C.
da Costa, Fernanda B.
Speziali, Nivaldo L.
Beraldo, Heloisa
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2010, 21 (07) : 1247 - 1257
[2] SYNTHESIS AND PHYSICOCHEMICAL STUDIES ON OXOVANADIUM(IV) COMPLEXES OF SUBSTITUTED MERCAPTOTRIAZINES
YADAV, S
SRIVASTAVA, S
PANDEY, OP
SENGUPTA, SK
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1994, 24 (06): : 925 - 939
[3] SYNTHESIS, CHARACTERIZATION AND ANTITUMOR-ACTIVITY OF IRON(II) AND IRON(III) COMPLEXES OF 3-SUBSTITUTED AND 5-SUBSTITUTED SALICYLALDEHYDE BENZOYL HYDRAZONES
MOHAN, M
GUPTA, NS
KUMAR, A
KUMAR, M
INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1987, 135 (03): : 167 - 177
[4] SYNTHESIS AND PHYSICOCHEMICAL INVESTIGATION OF HEXAFLUORO COMPLEXES OF GERMANIUM WITH MIXED-ALKALI METAL-CATIONS
ANTOKHINA, TF
SAVCHENKO, NN
IVANOV, SB
IGNATEVA, LN
KAVUN, VY
SERGIENKO, VI
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE, 1992, 41 (11): : 1941 - 1949
[5] Synthesis and physicochemical investigation of hexafluoride complexes NH(4)LiAF(6) (A=Si, Ge, Sn, and Ti)
Antokhina, TF
Kaidalova, TA
Ignateva, LN
Savchenko, NN
Gerasimenko, AV
ZHURNAL NEORGANICHESKOI KHIMII, 1996, 41 (04): : 598 - 601
[6] Cascade synthesis of substituted 4-amino-1,2,4-triazol-3-ones from aldehyde hydrazones and azodicarboxylates
Su, Yehua
Jiang, Zhen
Hong, Deng
Lu, Ping
Wang, Yanguang
Lin, Xianfu
TETRAHEDRON, 2010, 66 (13) : 2427 - 2432
[7] Synthesis and spectral characterization of ternary complexes of oxovanadium(IV) containing some acid hydrazones and 2,2′-bipyridine
Sreeja, PB
Kurup, MRP
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2005, 61 (1-2) : 331 - 336
[8] Dinuclear organotin(IV) complexes with bis-acyl-hydrazones containing flexible linker: Synthesis, spectroscopic investigation and crystal structure of dimethyl-and diphenyltin(IV) complexes with succinic dihydrazones
Sedaghat, Tahereh
Aminian, Marjan
Rudbari, Hadi Amiri
Bruno, Giuseppe
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 754 : 26 - 31
[9] Bis-substituted diphenylamine arylidene hydrazones for the synthesis of new binuclear organotin(IV) complexes: Crystal structure, DNA cleavage and molecular docking
Yousefi, Maryam
Sedaghat, Tahereh
Simpson, Jim
Motamedi, Hossein
Dayer, Mohammad Reza
POLYHEDRON, 2018, 155 : 153 - 162
[10] Zinc complexes of 3-(ethylthio)phenyl-substituted phthalocyanines and naphthalocyanine: Synthesis and investigation of physicochemical properties
Dubinina, Tatiana V.
Tychinsky, Pavel I.
Borisova, Nataliya E.
Maklakov, Sergey S.
Sedova, Marina V.
Kosov, Anton D.
Tomilova, Larisa G.
Zefirov, Nikolay S.
DYES AND PIGMENTS, 2017, 144 : 41 - 47

← 1 2 3 4 5 →