INTERACTIONS OF A SULFONATED IONOMER WITH SURFACTANT IN NONAQUEOUS MEDIA.

In the reported experiments, the viscometric behavior of dilute solutions of the sodium salt of sulfonated polystyrene(0-6 mol % sulfonation level), with and without surfactant, has been investigated to determine the extent of interaction as the structure of the solvent, surfactant, and polymer concentration is varied. Reduced viscosity measurements confirm that formation of a polymer-surfactant complex in a relatively polar solvent is controlled to a large extent by charge-charge and hydrophobic forces. The magnitude of these specific interactions is dependent upon the relative polarity of the solvent medium. In a polar solvent, such as dimethylsulfoxide, the hydrophobic forces are strong enough to prevent expansion of the polymer chain at all surfactant concentrations studied. The polystyrene-cationic surfactant complex exhibits a polyelectrolyte effect. In a lower-polarity medium (cyclohexanone) where the hydrophobic forces are weak, solution behavior is dominated by the interaction of the surfactant with the intramolecular sulfonate ion-pair aggregates.