MECHANISM OF THE SYNTHESIS OF OXYGEN-CONTAINING COMPOUNDS FROM CO AND H2.

被引：0

作者：

Slivinskii, E.V. ^{[1
]}

Rumyantsev, V.Yu. ^{[1
]}

Voitsekhovskii, Yu.P. ^{[1
]}

Zvezdkina, L.I. ^{[1
]}

Rozovskii, A.Ya. ^{[1
]}

Loktev, S.M. ^{[1
]}

机构：

[1] Acad of Sciences of the USSR, Moscow, USSR, Acad of Sciences of the USSR, Moscow, USSR

来源：

Kinetics and Catalysis | 1987年 / 28卷 / 2 pt 2期

关键词：

ALCOHOLS - Synthesis - CARBON MONOXIDE - Processing - CHEMICAL REACTIONS - Reaction Kinetics - HYDROCARBONS - Synthesis - HYDROGEN - Processing;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The work is devoted to a study of the mechanism of the formation of aldehydes, alcohols, and hydrocarbons in syntheses from CO and H//2 on a fused iron catalyst. It was shown that in the synthesis of aromatic alcohols and alkoxyalcohols on the basis of CO and H//2, the primary products are aldehydes, which are converted to alcohols and hydrocarbons as a result of secondary reactions. It is shown that the formation of aldehydes as primary products of the reaction of carbon monoxide and hydrogen provides a basis for believing that the hydrogenation of Co proceeds by successive addition of hydrogen to CO.

引用

页码：443 / 445

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