Synthesis and optical activity of polyamides derived from optically active spiro[3.3]heptane-2,6-dicarboxylic acid

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Graduate School of Materials Science, Japan Adv. Inst. Sci. and Technol., 1-1 Asahidai, Tatsunokuchi, Ishikawa 923-1292, Japan [1 ]
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Polym J | / 3卷 / 313-315期
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Acetone - Amines - Hydrogen bonds - Nitrogen compounds - Optical materials - Optical rotation - Organic solvents - Polycondensation - Reaction kinetics - Solubility - Sulfuric acid - Synthesis (chemical);
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摘要：
Optically active polymers are usually prepared by asymmetric polymerization, in which optical activity is induced via polymerization reaction using optically active catalyst or initiator from racemic or prochiral monomer. These polymers are formed from various type of monomers such as isocyanates, isocyanides, chlorals, and methacrylates. The synthesis and optical properties of polyamides derived from (R)-(+)-SHDAC and three diamine derivatives is described.
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