Oxidative Decarboxylation of Carboxylic Acids

被引：0
|
作者：
Serguchev, Yu.A. [1 ]
Beletskaya, I.P. [1 ]
机构：
[1] Institute of Organic Chemistry o f t h e A c a d e m y o f sciences of Ukrainian Lomonosov Moscow State University
来源：
Russian Chemical Reviews | 1980年 / 49卷 / 12期
关键词：
Carboxylation - Free radical reactions;
D O I：
10.1070/RC1980v049n12ABEH002532
中图分类号：
学科分类号：
摘要：
The present state of studies on thedecarboxylation of carboxylic acids by various oxidation systems is described and the dependence of theyield and composition of the reaction products on the structure of thecarboxylic acid, the type of oxidant and its ligand environment, the nature of the solvent, and the reaction mechanism is considered. The intermediate involvement of radicals and ions, produced by successive one-electron transfer processes, in the formation of a wide variety of decarboxylation products is discussed. © 1980 Turpion Ltd. All rights reserved.
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页码：1119 / 1134
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