KINETIC STUDY OF GAS-PHASE POLYMERIZATION OF PROPENE BY THE INHIBITION METHOD USING CARBON MONOXIDE.

被引:0
|
作者
Li, Yufei [1 ]
Tang, Shipei [1 ]
机构
[1] Beijing Research Inst of Chemical, Industry, Beijing, China, Beijing Research Inst of Chemical Industry, Beijing, China
来源
| 1985年 / 03期
关键词
CARBON MONOXIDE - Applications - POLYMERIZATION - Reaction Kinetics;
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中图分类号
学科分类号
摘要
The inhibition method using CO to determine the active center concentration C* in olefin polymerization and the kinetics of gas-phase polymerization of propene were studied. The reliability of the method when used in gas-phase polymerization of propene is proved and the influencing factor of the method is found to be the 'repeating inhibition' of CO to the active centers. The C*, the rate constant k//P and the activation energy were determined from the experimental results.
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