Synthesis and radical polymerization of novel methacrylates with mesoionic 6-oxo-1,6-dihydropyrimidin-3-ium-4-olates as photosensitive components

被引：0

作者：

Theis, A. ^{[1
]}

Ritter, H. ^{[1
]}

机构：

[1] Johannes Gutenberg Univ. Mainz, Institut für Organische Chemie, Duesbergweg 10-14, 55128 Mainz, Germany

来源：

| 2001年 / VSP BV卷 / 04期

关键词：

Lactames - Mesoionic compounds - Methacrylates - Oxodihydropyrimidiniumolates - Photosensitive polymers;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

New polymerizable mesoionic 6-oxo-1,6-dihydropyrimidin-3-ium-4-olates 5a-f have been synthesized using tosylated 2-hydroxymethyl methacrylate and various thioureas and malonic acids. Radical polymerization of the mesoionic derivatives 5a, c, d, e with AIBN as initiator resulted in soluble polymers, which were used for the preparation of photosensitive films.

引用

共 17 条

[1] Synthesis and radical polymerization of novel methacrylates with mesoionic 6-oxo-1,6-dihydropyrimidin-3-ium-4-olates as photosensitive components
Theis, A
Ritter, H
DESIGNED MONOMERS AND POLYMERS, 2001, 4 (02) : 177 - 194
[2] Cyclodextrins in polymer synthesis:: Free radical polymerization of β-cyclodextrin complexes of photosensitive mesoionic 6-oxo-1,6-dihydropyrimidin-3-ium-4-olates in aqueous medium
Theis, A
Ritter, H
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2003, 204 (10) : 1297 - 1304
[3] Synthesis of a polyphenol with a mesoionic 6-oxo-1,6-dihydropyrimidin-3-ium-4-olate as pendant group and its photochemical behavior
Tonami, H
Uyama, H
Kobayashi, S
Menges, B
Mittler, S
Theis, A
Ritter, H
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2003, 204 (08) : 1079 - 1084
[4] MESOIONIC 6-MEMBERED HETEROCYCLES .1. SYNTHESIS OF 6-OXO-6H-1,3-OXAZIN-3-IUM-4-OLATES
FRIEDRICHSEN, W
KUJATH, E
LIEBEZEIT, G
SCHMIDT, R
SCHWARZ, I
JUSTUS LIEBIGS ANNALEN DER CHEMIE, 1978, (10): : 1655 - 1665
[5] MESOIONIC 6-MEMBERED HETEROCYCLES, .6. REACTIONS OF 6-OXO-6H-1, 3-OXAZIN-3-IUM-4-OLATES WITH CARBODIIMIDES
FRIEDRICHSEN, W
SCHILDBERG, M
HETEROCYCLES, 1983, 20 (03) : 431 - 434
[6] Design, synthesis, and biological evaluation of N-(3-cyano-1H-indol-5/ 6-yl)-6-oxo-1,6-dihydropyrimidine-4-carboxamides and 5-(6-oxo-1,6-dihydropyrimidin-2-yl)-1H-indole-3-carbonitriles as novel xanthine oxidase inhibitors
Zhang, Bing
Duan, Yulin
Yang, Yuwei
Mao, Qing
Lin, Fengwei
Gao, Jun
Dai, Xiwen
Zhang, Peng
Li, Qiuhua
Li, Jinxin
Dai, Ronghua
Wang, Shaojie
EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2022, 227
[7] MESOIONIC 6-MEMBERED HETEROCYCLES, .5. REACTIONS OF 6-OXO-6H-1,3-OXAZIN-3-IUM-4-OLATES WITH OMICRON-QUINONES AND HETEROCUMULENES
FRIEDRICHSEN, W
KUJATH, E
LIEBEZEIT, G
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1982, 37 (02): : 222 - 233
[8] Preparation and optimization of new 4-(morpholin-4-yl)-(6-oxo-1,6-dihydropyrimidin-2-yl) amide derivatives as PI3Kβ inhibitors
Certal, Victor
Halley, Frank
Virone-Oddos, Angela
Thompson, Fabienne
Filoche-Romme, Bruno
El-Ahmad, Youssef
Carry, Jean-Christophe
Delorme, Cecile
Karlsson, Andreas
Abecassis, Pierre-Yves
Vincent, Loic
Bonnevaux, Helene
Nicolas, Jean-Paul
Morales, Renaud
Michot, Nadine
Vade, Isabelle
Louboutin, Audrey
Perron, Sebastien
Doerflinger, Gilles
Tric, Bernadette
Monget, Sylvie
Lengauer, Christoph
Schio, Laurent
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2012, 22 (20) : 6381 - 6384
[9] NOVEL 1,4-DIPOLAR CYCLO-ADDITION REACTIONS OF 6-OXO-6H-1,3-OXAZIN-3-IUM-4-OLATES AND OF A 6-OXO-6H-1,3-THIAZIN-3-IUM-4-OLATE TO KETENE DERIVATIVES AND ENAMINES
GOTTHARDT, H
FLOSBACH, C
CHEMISCHE BERICHTE-RECUEIL, 1988, 121 (05): : 951 - 960
[10] 2,6-diamino-5-(2,4-diamino-6-oxo-1,6-dihydropyrimidin-5-ylmethyl)-4-oxo-pyrimidin-1-ium 3,5-dinitrobenzoate
Subashini, Annamalai
Muthiah, Packianathan Thomas
Bocelli, Gabriele
Cantoni, Andrea
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4408 - U4268

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